Intermetallic nanocrystals for fuel-cells-based electrocatalysis

F Lin, M Li, L Zeng, M Luo, S Guo - Chemical Reviews, 2023 - ACS Publications
Electrocatalysis underpins the renewable electrochemical conversions for sustainability,
which further replies on metallic nanocrystals as vital electrocatalysts. Intermetallic …

A theory/experience description of support effects in carbon-supported catalysts

IC Gerber, P Serp - Chemical Reviews, 2019 - ACS Publications
The support plays an important role for supported metal catalysts by positioning itself as a
macromolecular ligand, which conditions the nature of the active site and contributes …

Low-temperature catalytic NO reduction with CO by subnanometric Pt clusters

E Fernandez, L Liu, M Boronat, R Arenal… - ACS …, 2019 - ACS Publications
The catalytic subnanometric metal clusters with a few atoms can be regarded as an
intermediate state between single atoms and metal nanoparticles (> 1 nm). Their molecule …

Selectivity for ethanol partial oxidation: the unique chemistry of single-atom alloy catalysts on Au, Ag, and Cu (111)

H Li, W Chai, G Henkelman - Journal of Materials Chemistry A, 2019 - pubs.rsc.org
Recently, we found that the atomic ensemble effect is the dominant effect influencing
catalysis on surfaces alloyed with strong-and weak-binding elements, determining the …

Template‐guided regioselective encaging of platinum single atoms into Y zeolite: Enhanced selectivity in semihydrogenation and resistance to poisoning

Q Chen, P Peng, G Yang, Y Li, M Han… - Angewandte Chemie …, 2022 - Wiley Online Library
It is challenging to establish single metal atoms with a uniform coordination environment at
targeted sites of a zeolite. In this study, single platinum atoms were selectively encaged in …

Benzene abatement catalyzed by ceria-supported platinum nanoparticles and single atoms

J Liu, X Fang, D Liu, X Hu, T Qin, J Chen, R Liu… - Chemical Engineering …, 2023 - Elsevier
Heterogeneous catalysis is one promising technology to abate benzene at relatively low
temperatures, but it remains challenging to develop efficient catalysts owing to the difficulties …

Recent progress on sulfated nanozirconia as a solid acid catalyst in the hydrocracking reaction

SJ Sekewael, RA Pratika, L Hauli, AK Amin, M Utami… - Catalysts, 2022 - mdpi.com
Zirconia has advantageous thermal stability and acid–base properties. The acidity character
of ZrO2 can be enhanced through the sulfation process forming sulfated zirconia (ZrO2 …

Following Adsorbed Intermediates on a Platinum Gas Diffusion Electrode in H3PO3-Containing Electrolytes Using In Situ X-ray Absorption Spectroscopy

BF Gomes, M Prokop, T Bystron, R Loukrakpam… - ACS …, 2022 - ACS Publications
One of the challenges of high-temperature polymer electrolyte membrane fuel cells is the
poisoning of the Pt catalyst with H3PO4. H3PO4 is imbibed into the routinely used …

Predicting the strength of metal–support interaction with computational descriptors for adhesion energies

EM Dietze, PN Plessow - The Journal of Physical Chemistry C, 2019 - ACS Publications
Interfaces play an important role in heterogeneous catalysis where oxides are typically used
as supports to stabilize catalytically active transition metal particles and to tune their …

Tuning the interfacial interactions between alumina support and pseudo single atom platinum-tin catalytic sites for heavy naphtha reforming

R Belgamwar, K Santhosh, G Valavarasu, P Sarawade… - Catalysis Today, 2024 - Elsevier
Heavy naphtha reforming, a crucial downstream process in oil refineries for improving the
octane number of the gasoline feedstock, requires expensive Pt metal catalysts and it …