The renaissance of non‐aqueous uranium chemistry
ST Liddle - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
Nonaqueous Electrochemistry of Uranium Complexes: A Guide to Structure–Reactivity Tuning
J Riedhammer, DP Halter, K Meyer - Chemical Reviews, 2023 - ACS Publications
Uranium complexes can be stabilized in a wide range of oxidation states, ranging from UII to
UVI and a very recent example of a UI complex. This review provides a comprehensive …
UVI and a very recent example of a UI complex. This review provides a comprehensive …
A flexible electromagnetic wave-electricity harvester
Develo** an ultimate electromagnetic (EM)-absorbing material that can not only dissipate
EM energy but also convert the generated heat into electricity is highly desired but remains a …
EM energy but also convert the generated heat into electricity is highly desired but remains a …
31P Nuclear Magnetic Resonance Spectroscopy as a Probe of Thorium–Phosphorus Bond Covalency: Correlating Phosphorus Chemical Shift to Metal–Phosphorus …
We report the use of solution and solid-state 31P Nuclear Magnetic Resonance (NMR)
spectroscopy combined with Density Functional Theory calculations to benchmark the …
spectroscopy combined with Density Functional Theory calculations to benchmark the …
Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl6x– (x = 3, 2)
Covalency in Ln–Cl bonds of O h-LnCl6 x–(x= 3 for Ln= CeIII, NdIII, SmIII, EuIII, GdIII; x= 2 for
Ln= CeIV) anions has been investigated, primarily using Cl K-edge X-ray absorption …
Ln= CeIV) anions has been investigated, primarily using Cl K-edge X-ray absorption …
Energy-degeneracy-driven covalency in actinide bonding
Evaluating the nature of chemical bonding for actinide elements represents one of the most
important and long-standing problems in actinide science. We directly address this …
important and long-standing problems in actinide science. We directly address this …
High-energy resolution X-ray spectroscopy at actinide M 4, 5 and ligand K edges: what we know, what we want to know, and what we can know
In recent years, scientists have progressively recognized the role of electronic structures in
the characterization of chemical properties for actinide containing materials. High-energy …
the characterization of chemical properties for actinide containing materials. High-energy …
Influence of Pyrazolate vs N-Heterocyclic Carbene Ligands on the Slow Magnetic Relaxation of Homoleptic Trischelate Lanthanide(III) and Uranium(III) Complexes
KR Meihaus, SG Minasian, WW Lukens Jr… - Journal of the …, 2014 - ACS Publications
Two isostructural series of trigonal prismatic complexes, M (BpMe) 3 and M (BcMe) 3 (M= Y,
Tb, Dy, Ho, Er, U;[BpMe]−= dihydrobis (methypyrazolyl) borate;[BcMe]−= dihydrobis …
Tb, Dy, Ho, Er, U;[BpMe]−= dihydrobis (methypyrazolyl) borate;[BcMe]−= dihydrobis …
Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis
Determining the nature and extent of covalency of early actinide chemical bonding is a
fundamentally important challenge. Recently, X-ray absorption, electron paramagnetic, and …
fundamentally important challenge. Recently, X-ray absorption, electron paramagnetic, and …
Ab initio ligand-field theory analysis and covalency trends in actinide and lanthanide free ions and octahedral complexes
Actinide chemistry is gaining increased focus in modern research, particularly in the fields of
energy research and molecular magnetism. However, the structure–function and structure …
energy research and molecular magnetism. However, the structure–function and structure …