Recent advances in stable main group element radicals: preparation and characterization
Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …
novel physicochemical properties play significant roles not only in fundamental chemistry …
Heteroatom-based diradical (oid) s
Heteroatom-centered diradical (oid) s have been in the focus of molecular main group
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …
Boron-containing organic diradicaloids: dynamically modulating singlet diradical character by lewis acid–base coordination
J Guo, Y Yang, C Dou, Y Wang - Journal of the American …, 2021 - ACS Publications
Organic diradicaloids have unique open-shell structures and properties and promising
applications in organic electronics and spintronics. Incorporation of heteroatoms is an …
applications in organic electronics and spintronics. Incorporation of heteroatoms is an …
Efficient Narrowband Circularly Polarized Light Emitters Based on 1, 4‐B, N‐embedded Rigid Donor–Acceptor Helicenes
Narrow‐band emission is essential for applicable circularly polarized luminescence (CPL)
active materials in ultrahigh‐definition CP‐OLEDs. One of the most promising classes of …
active materials in ultrahigh‐definition CP‐OLEDs. One of the most promising classes of …
Diradical B/N‐Doped Polycyclic Hydrocarbons
J Guo, Z Li, X Tian, T Zhang, Y Wang… - Angewandte …, 2023 - Wiley Online Library
Heterocyclic diradicaloids with atom‐precise control over open‐shell nature are promising
materials for organic electronics and spintronics. Herein, we disclose quinoidal π‐extension …
materials for organic electronics and spintronics. Herein, we disclose quinoidal π‐extension …
Dark State of the Thiele Hydrocarbon: Efficient Solvatochromic Emission from a Nonpolar Centrosymmetric Singlet Diradicaloid
In this work, a comprehensive investigation of the photoinduced processes and mechanisms
linked to the luminescence of a novel nonperchlorinated Thiele hydrocarbon (TTH) is …
linked to the luminescence of a novel nonperchlorinated Thiele hydrocarbon (TTH) is …
Ammonia Synthesis at Room Temperature and Atmospheric Pressure from N2: A Boron‐Radical Approach
S Bennaamane, B Rialland, L Khrouz… - Angewandte Chemie …, 2023 - Wiley Online Library
Ammonia, NH3, is an essential molecule, being part of fertilizers. It is currently synthesized
via the Haber–Bosch process, from the very stable dinitrogen molecule, N2 and dihydrogen …
via the Haber–Bosch process, from the very stable dinitrogen molecule, N2 and dihydrogen …
A platform for blue-luminescent carbon-centered radicals
X Li, YL Wang, C Chen, YY Ren, YF Han - Nature Communications, 2022 - nature.com
Organic radicals, which have unique doublet spin-configuration, provide an alternative
method to overcome the efficiency limitation of organic light-emitting diodes (OLEDs) based …
method to overcome the efficiency limitation of organic light-emitting diodes (OLEDs) based …
A crystalline radical cation derived from Thiele's hydrocarbon with redox range beyond 1 V
Thiele's hydrocarbon occupies a central role as an open-shell platform for new organic
materials, however little is known about its redox behaviour. While recent synthetic …
materials, however little is known about its redox behaviour. While recent synthetic …
Direct visible-light-induced synthesis of P-stereogenic phosphine oxides under air conditions
Y Zhang, J Yuan, G Huang, H Yu, J Liu, J Chen… - Chemical …, 2022 - pubs.rsc.org
Over the past two decades, visible-light-induced transformations have been regarded as
being among the most environmentally benign and powerful strategies for constructing …
being among the most environmentally benign and powerful strategies for constructing …