Endohedral fullerenes
AA Popov, S Yang, L Dunsch - Chemical reviews, 2013 - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …
possibility to use them as robust containers for other species. Although an IUPAC …
When metal clusters meet carbon cages: endohedral clusterfullerenes
S Yang, T Wei, F ** - Chemical society reviews, 2017 - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …
Dearomative Ring‐Fused Azafulleroids and Carbazole‐Derived Metallofullerenes: Reactivity Dictated by Encapsulation in a Fullerene Cage
Herein, we report divergent additions of 2, 2′‐diazidobiphenyls to C60 and Sc3N@ Ih‐
C80. In stark contrast to that of the previously reported bis‐azide additions, the unexpected …
C80. In stark contrast to that of the previously reported bis‐azide additions, the unexpected …
Exohedral functionalization of endohedral metallofullerenes: Interplay between inside and outside
Endohedral metallofullerenes (EMFs) are fullerene cages enclosing various metallic
species. The functionalization of EMFs has remarkably blossomed in recent years, in …
species. The functionalization of EMFs has remarkably blossomed in recent years, in …
Unexpected formation of metallofulleroids from multicomponent reactions, with crystallographic and computational studies of the cluster motion
New multicomponent reactions involving an isocyanide, terminal or internal alkynes, and
endohedral metallofullerene (EMF) Lu3N@ C80 yield metallofulleroids which are …
endohedral metallofullerene (EMF) Lu3N@ C80 yield metallofulleroids which are …
Unexpected Formation of Pyrazoline-Fused Metallofullerenes from the Multicomponent Cascade Reaction of Sc3N@Ih-C80 with Tetrazines, Water, and Oxygen
C Niu, Z Liu, M Chen, S Yang, GW Wang - Organic Letters, 2022 - ACS Publications
The multicomponent cascade reaction of Sc3N@ I h-C80 with 3, 6-di (pyridin-2-yl)-1, 2, 4, 5-
tetrazines, water, and oxygen unexpectedly affords the pyrazoline-fused Sc3N@ I h-C80 …
tetrazines, water, and oxygen unexpectedly affords the pyrazoline-fused Sc3N@ I h-C80 …
[ΒΙΒΛΙΟ][B] Endohedral Metallofullerenes: Basics and Applications
X Lu, L Echegoyen, AL Balch, S Nagase, T Akasaka - 2014 - books.google.com
Knowledge on endohedral metallofullerenes (EMFs) has increased dramatically during the
last decade. Numerous research findings have been reported, making it an opportune time …
last decade. Numerous research findings have been reported, making it an opportune time …
Decisive role of non-rare earth metals in high-regioselectivity addition of μ 3-carbido clusterfullerene
Endohedral clusterfullerenes featuring encapsulation of metal clusters which transfer
electrons to the outer fullerene cages show intriguing chemical properties different from …
electrons to the outer fullerene cages show intriguing chemical properties different from …
Prato Reaction of M3N@Ih-C80 (M = Sc, Lu, Y, Gd) with Reversible Isomerization
S Aroua, Y Yamakoshi - Journal of the American Chemical …, 2012 - ACS Publications
The 1, 3-dipolar cycloaddition of an azomethine ylide (Prato reaction) with M3N@ I h-C80
(denoted as M3N@ C80; M= Sc, Lu, Y, Gd) was carried out to obtain fulleropyrrolidinebis …
(denoted as M3N@ C80; M= Sc, Lu, Y, Gd) was carried out to obtain fulleropyrrolidinebis …
(2 + 2) Cycloaddition of Benzyne to Endohedral Metallofullerenes M3N@C80 (M = Sc, Y): A Rotating-Intermediate Mechanism
The reaction mechanism and origin of regioselectivity of (2+ 2) cycloadditions of benzyne to
endohedral metallofullerenes M3N@ C80 (M= Sc, Y) were investigated with density …
endohedral metallofullerenes M3N@ C80 (M= Sc, Y) were investigated with density …