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Alkali-metal-mediated synergistic effects in polar main group organometallic chemistry
SD Robertson, M Uzelac, RE Mulvey - Chemical Reviews, 2019 - ACS Publications
The development of synthetic chemistry since the early 1900s owes much to the service of
organolithium reagents. Brilliant bases (eg, deprotonating C–H bonds), nucleophiles (eg …
organolithium reagents. Brilliant bases (eg, deprotonating C–H bonds), nucleophiles (eg …
Sodium diisopropylamide: aggregation, solvation, and stability
RF Algera, Y Ma, DB Collum - Journal of the American Chemical …, 2017 - ACS Publications
The solution structures, stabilities, physical properties, and reactivities of sodium
diisopropylamide (NaDA) in a variety of coordinating solvents are described. NaDA is stable …
diisopropylamide (NaDA) in a variety of coordinating solvents are described. NaDA is stable …
Synthesis of a sterically demanding dispiropiperidine and its application in monoamidodialkyl zincate complexes
The new sterically hindered piperidine analog, dispiro [cyclohexane-2, 2′-piperidine-6′, 2
″-cyclohexane](CPC (H), 2), and its N-methylated derivative CPC (Me)(3) were synthesized …
″-cyclohexane](CPC (H), 2), and its N-methylated derivative CPC (Me)(3) were synthesized …