Photo-CIDNP spectroscopy relies on a unique interplay of magnetic interactions, diffusion,
and chemical reactivity; it possesses all the advantages of NMR spectroscopy but responds …

In this chapter, we explore experimental and theoretical aspects of molecular wire-like
charge transport from the mechanistic point of view. We discuss competition between …

An EPR" spectroscopic ruler" was developed using a series of alpha-helical polypeptides,
each modified with two nitroxide spin labels. The EPR line broadening due to electron …

Functional molecular wires are essential for the development of molecular electronics.
Charge transport through molecules occurs primarily by means of two mechanisms …

The second edition of this best-selling handbook is bigger, more comprehensive, and now
completely current. In addition to thorough updates to the discussions featured in the first …

0009-2665/93/0793-0537 $12.00/0 panding area of chemical physics and physical
chemistry (for reviews see refs 1-6). The developmentof the discipline has been driven by an …

A method was developed to determine the interspin distances of two or more nitroxide spin
labels attached to specific sites in proteins. This method was applied to different …

A stable 2, 2, 6, 6-tetramethyl-1-piperidinyloxyl (TEMPO) radical was covalently attached at
its 4-position to the imide nitrogen atom of a perylene-3, 4: 9, 10-bis (dicarboximide)(PDI) to …

The experimental technique of time-resolved (direct detection) electron paramagnetic
resonance (TREPR) spectroscopy, and its role in the elucidation of free-radical structure …

Structural and dynamical characterization of proteins is of central importance in
understanding the mechanisms underlying their biological functions. Site-directed spin …