Thermodynamic and kinetic hydricities of metal-free hydrides
Metal-free hydrides are of increasing research interest due to their roles in recent scientific
advances in catalysis, such as hydrogen activation with frustrated Lewis pairs and …
advances in catalysis, such as hydrogen activation with frustrated Lewis pairs and …
Correlating Thermodynamic and Kinetic Hydricities of Rhenium Hydrides
MR Espinosa, MZ Ertem, M Barakat… - Journal of the …, 2022 - ACS Publications
The kinetics of hydride transfer from Re (Rbpy)(CO) 3H (bpy= 4, 4′-R-2, 2′-bipyridine; R=
OMe, tBu, Me, H, Br, COOMe, CF3) to CO2 and seven different cationic N-heterocycles were …
OMe, tBu, Me, H, Br, COOMe, CF3) to CO2 and seven different cationic N-heterocycles were …
Thermodynamic hydricities of biomimetic organic hydride donors
Thermodynamic hydricities (Δ GH–) in acetonitrile and dimethyl sulfoxide have been
calculated and experimentally measured for several metal-free hydride donors: NADH …
calculated and experimentally measured for several metal-free hydride donors: NADH …
Tetradentate C∧C∧N∧N Ligand-Containing Gold(III) Complexes with Orange to Deep-Red Thermally Activated Delayed Fluorescence (TADF) and Their …
WK Kwok, LK Li, SL Lai, MY Leung… - Journal of the …, 2023 - ACS Publications
A new class of thermally activated delayed fluorescence (TADF) tetradentate C∧ C∧ N∧ N
ligand-containing gold (III) complexes containing acridinyl moieties has been designed and …
ligand-containing gold (III) complexes containing acridinyl moieties has been designed and …
Photodriven Ammonia Synthesis from Manganese Nitrides: Photophysics and Mechanistic Investigations
Ammonia synthesis from N, N, O, O-supported manganese (V) nitrides and 9, 10-
dihydroacridine using proton-coupled electron transfer and visible light irradiation in the …
dihydroacridine using proton-coupled electron transfer and visible light irradiation in the …
Photoswitchable hydride transfer from iridium to 1-methylnicotinamide rationalized by thermochemical cycles
SM Barrett, CL Pitman, AG Walden… - Journal of the American …, 2014 - ACS Publications
Visible light-triggered hydride transfer from [Cp* Ir (bpy)(H)]+(1) to organic acids and 1-
methylnicotinamide (MNA+) is reported (Cp*= pentamethylcyclopentadienyl; bpy= 2, 2 …
methylnicotinamide (MNA+) is reported (Cp*= pentamethylcyclopentadienyl; bpy= 2, 2 …
A bioinspired disulfide/dithiol redox switch in a rhenium complex as proton, H atom, and hydride transfer reagent
SA Hua, LA Paul, M Oelschlegel… - Journal of the …, 2021 - ACS Publications
The transfer of multiple electrons and protons is of crucial importance in many reactions
relevant in biology and chemistry. Natural redox-active cofactors are capable of storing and …
relevant in biology and chemistry. Natural redox-active cofactors are capable of storing and …
Design and synthesis of phenylacridine-based on organic dyes and its applications in dye-sensitized solar cells
T Saravana Kumaran, A Prakasam… - Russian Journal of …, 2023 - Springer
Dimethylphenyldihydroacridine dyes are an important type of organic molecule that are
used in dye-sensitized solar cells. Two new organic dyes, namely (E)-3-(7-bromo-9, 9 …
used in dye-sensitized solar cells. Two new organic dyes, namely (E)-3-(7-bromo-9, 9 …
Exploring the molecular design principles for efficient diarylethene photoacid and photohydride generators based on the photochemical reaction mechanism
Y Su, D Zheng, L Ge, L Yu, DL Phillips, J Ma… - Chemical Science, 2024 - pubs.rsc.org
Photoacid generators (PAGs) and photohydride generators (PHGs) are specific photolabile
protecting groups that release acid and hydride, respectively. Over the past decade, great …
protecting groups that release acid and hydride, respectively. Over the past decade, great …
Light-driven reduction of CO 2: thermodynamics and kinetics of hydride transfer reactions in benzimidazoline derivatives
CO2 capture, conversion and storage belong to the holy grail of environmental science. We
therefore explore an important photochemical hydride transfer reaction of benzimidazoline …
therefore explore an important photochemical hydride transfer reaction of benzimidazoline …