Thermodynamic and kinetic hydricities of metal-free hydrides

S Ilic, A Alherz, CB Musgrave, KD Glusac - Chemical Society Reviews, 2018 - pubs.rsc.org
Metal-free hydrides are of increasing research interest due to their roles in recent scientific
advances in catalysis, such as hydrogen activation with frustrated Lewis pairs and …

Correlating Thermodynamic and Kinetic Hydricities of Rhenium Hydrides

MR Espinosa, MZ Ertem, M Barakat… - Journal of the …, 2022 - ACS Publications
The kinetics of hydride transfer from Re (Rbpy)(CO) 3H (bpy= 4, 4′-R-2, 2′-bipyridine; R=
OMe, tBu, Me, H, Br, COOMe, CF3) to CO2 and seven different cationic N-heterocycles were …

Thermodynamic hydricities of biomimetic organic hydride donors

S Ilic, U Pandey Kadel, Y Basdogan… - Journal of the …, 2018 - ACS Publications
Thermodynamic hydricities (Δ GH–) in acetonitrile and dimethyl sulfoxide have been
calculated and experimentally measured for several metal-free hydride donors: NADH …

Tetradentate CCNN Ligand-Containing Gold(III) Complexes with Orange to Deep-Red Thermally Activated Delayed Fluorescence (TADF) and Their …

WK Kwok, LK Li, SL Lai, MY Leung… - Journal of the …, 2023 - ACS Publications
A new class of thermally activated delayed fluorescence (TADF) tetradentate C∧ C∧ N∧ N
ligand-containing gold (III) complexes containing acridinyl moieties has been designed and …

Photodriven Ammonia Synthesis from Manganese Nitrides: Photophysics and Mechanistic Investigations

GB Panetti, J Kim, MS Myong, MJ Bird… - Journal of the …, 2024 - ACS Publications
Ammonia synthesis from N, N, O, O-supported manganese (V) nitrides and 9, 10-
dihydroacridine using proton-coupled electron transfer and visible light irradiation in the …

Photoswitchable hydride transfer from iridium to 1-methylnicotinamide rationalized by thermochemical cycles

SM Barrett, CL Pitman, AG Walden… - Journal of the American …, 2014 - ACS Publications
Visible light-triggered hydride transfer from [Cp* Ir (bpy)(H)]+(1) to organic acids and 1-
methylnicotinamide (MNA+) is reported (Cp*= pentamethylcyclopentadienyl; bpy= 2, 2 …

A bioinspired disulfide/dithiol redox switch in a rhenium complex as proton, H atom, and hydride transfer reagent

SA Hua, LA Paul, M Oelschlegel… - Journal of the …, 2021 - ACS Publications
The transfer of multiple electrons and protons is of crucial importance in many reactions
relevant in biology and chemistry. Natural redox-active cofactors are capable of storing and …

Design and synthesis of phenylacridine-based on organic dyes and its applications in dye-sensitized solar cells

T Saravana Kumaran, A Prakasam… - Russian Journal of …, 2023 - Springer
Dimethylphenyldihydroacridine dyes are an important type of organic molecule that are
used in dye-sensitized solar cells. Two new organic dyes, namely (E)-3-(7-bromo-9, 9 …

Exploring the molecular design principles for efficient diarylethene photoacid and photohydride generators based on the photochemical reaction mechanism

Y Su, D Zheng, L Ge, L Yu, DL Phillips, J Ma… - Chemical Science, 2024 - pubs.rsc.org
Photoacid generators (PAGs) and photohydride generators (PHGs) are specific photolabile
protecting groups that release acid and hydride, respectively. Over the past decade, great …

Light-driven reduction of CO 2: thermodynamics and kinetics of hydride transfer reactions in benzimidazoline derivatives

BD Ostojić, B Stanković, DS Đorđević… - Physical Chemistry …, 2022 - pubs.rsc.org
CO2 capture, conversion and storage belong to the holy grail of environmental science. We
therefore explore an important photochemical hydride transfer reaction of benzimidazoline …