In the past few years, Pd-catalyzed annulation reactions through zwitterionic π-allyl
palladium intermediates have been extensively investigated. Meanwhile, zwitterionic π-allyl …

The enantioselective catalytic cascade involving Tsuji–Trost allylation has provided a viable
strategy for the construction of multiple asymmetric C–C and C–X centres and numerous …

Abstract The asymmetric synthesis of 2, 2‐difluorinated tetrahydrofurans was accomplished
via enantioselective formal [3+ 2] cycloaddition catalyzed by palladium. The asymmetric …

Herein, a practical and efficient approach to tetrahydrofurans with three-stereocenters has
been developed through Pd-catalyzed asymmetric allylic cycloaddition of vinylethylene …

An efficient method for the synthesis of functionalized chiral tetrahydrofuran (THF) acetals
via Pd-catalyzed asymmetric allylic cycloaddition has been developed. With a palladium …

The activated alkynes have been used successfully for the first time as the dipolarophile in
the palladium-catalyzed asymmetric (3+ 2) cycloaddition, affording highly functionalized …

Alkynyl esters are viable dipolarophiles for the palladium-catalyzed asymmetric (3+ 2)
cycloaddition with vinyl epoxides. The chiral dihydrofurans are obtained in high yields and …

A Pd-catalyzed asymmetric decarboxylative [4+ 2] cycloaddition of 3-nitroindoles and vinyl
benzoxazinanones is developed through a dearomatization approach. The reaction …

Chiral heterocyclic compounds are an important class of chiral substances, which are
widespread in many chiral drugs, pesticides and catalysts. Therefore, the efficient …

An unprecedented asymmetric γ‐allylic alkylation of free dienolates via Sc/Ir dual catalysis is
reported, which affords a range of synthetically versatile γ‐allylic crotonaldehydes in high …