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The synthesis, properties and potential applications of cyclic polymers
Unlike their more common linear counterparts, cyclic polymers have a ring-like structure and
a lack of chain ends. Because of their topology, cyclic polymers exhibit a unique set of …
a lack of chain ends. Because of their topology, cyclic polymers exhibit a unique set of …
Cyclic polymers: Advances in their synthesis, properties, and biomedical applications
R Liénard, J De Winter… - Journal of Polymer …, 2020 - Wiley Online Library
Since the time first synthetic macrocycles were observed as academic curiosities, great
advances have been made. Thanks to the development of controlled polymerization …
advances have been made. Thanks to the development of controlled polymerization …
Designing high χ copolymer materials for nanotechnology applications: A systematic bulk vs. thin films approach
This review article discusses the origins of self-assembly behavior of linear and non-linear
block co-and terpolymers and their application towards the fabrication of high-resolution …
block co-and terpolymers and their application towards the fabrication of high-resolution …
Synthesis, properties, and applications of bio-based cyclic aliphatic polyesters
Cyclic polymers have long been reported in the literature, but their development has often
been stunted by synthetic difficulties such as the presence of linear contaminants. Research …
been stunted by synthetic difficulties such as the presence of linear contaminants. Research …
Enhanced dielectric strength and capacitive energy density of cyclic polystyrene films
The maximum capacitive energy stored in polymeric dielectric capacitors, which are
ubiquitous in high-power-density devices, is dictated by the dielectric breakdown strength of …
ubiquitous in high-power-density devices, is dictated by the dielectric breakdown strength of …
Scaling exponent and effective interactions in linear and cyclic polymer solutions: Theory, simulations, and experiments
Cyclic polymers have garnered increasing attention in the materials community as lack of
free-chain ends in cyclic polymers results in significant differences in structure …
free-chain ends in cyclic polymers results in significant differences in structure …
Micelles with cyclic poly (ε-caprolactone) moieties: greater stability, larger drug loading capacity, and slower degradation property for controlled drug release
G Kang, L Sun, Y Liu, C Meng, W Ma, B Wang, L Ma… - Langmuir, 2019 - ACS Publications
Polymer topology exerts a significant effect on its properties and performance for potential
applications. Cyclic topology and its derived structures have been recently shown to …
applications. Cyclic topology and its derived structures have been recently shown to …
Cyclic topology enhancing structural ordering and stability of comb-shaped polypeptoid thin films against melt-induced dewetting
We investigated the effect of cyclic chain topology on the molecular ordering and thermal
stability of comb-shaped polypeptoid thin films on silicon (Si) substrates. Cyclic and linear …
stability of comb-shaped polypeptoid thin films on silicon (Si) substrates. Cyclic and linear …
Impact of cyclic block copolymer chain architecture and degree of polymerization on nanoscale domain spacing: A simulation and scaling theory analysis
Cyclic block copolymers are predicted to assemble into nanostructured domains up to 40%
smaller than their linear analogues, making them promising alternatives for nanoscale …
smaller than their linear analogues, making them promising alternatives for nanoscale …
Metal Ion Selective Self‐Assembly of a Ligand Functionalized Polymer into [1+ 1] Macrocyclic and Supramolecular Polymer Structures via Metal–Ligand Coordination
The design and synthesis of polymer‐based metallomacrocycles relying on metal–ligand
interactions remain a challenge in the polymer field. Instead of utilizing chemical reactions to …
interactions remain a challenge in the polymer field. Instead of utilizing chemical reactions to …