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Recent progress in the science of complex coacervation
Complex coacervation is an associative, liquid–liquid phase separation that can occur in
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …
50th Anniversary Perspective: A Perspective on Polyelectrolyte Solutions
From the beginning of life with the information-containing polymers until the present era of a
plethora of water-based materials in health care industry and biotechnology, polyelectrolytes …
plethora of water-based materials in health care industry and biotechnology, polyelectrolytes …
Complete phase diagram for liquid–liquid phase separation of intrinsically disordered proteins
A number of intrinsically disordered proteins have been shown to self-assemble via liquid–
liquid phase separation into protein-rich and dilute phases. The resulting coacervates can …
liquid phase separation into protein-rich and dilute phases. The resulting coacervates can …
Polyelectrolyte complex coacervates: Recent developments and new frontiers
Polyelectrolyte complex coacervates represent a wide class of materials with applications
ranging from coatings and adhesives to pharmaceutical technologies. They also underpin …
ranging from coatings and adhesives to pharmaceutical technologies. They also underpin …
Development of the modern theory of polymeric complex coacervation
Oppositely charged polymers can undergo the process of complex coacervation, which
refers to a liquid–liquid phase separation driven by electrostatic attraction. These materials …
refers to a liquid–liquid phase separation driven by electrostatic attraction. These materials …
Designing electrostatic interactions via polyelectrolyte monomer sequence
Charged polymers are ubiquitous in biological systems because electrostatic interactions
can drive complicated structure formation and respond to environmental parameters such as …
can drive complicated structure formation and respond to environmental parameters such as …
[HTML][HTML] Theory of polyelectrolyte complexation—Complex coacervates are self-coacervates
The complexation of mixtures of cationic and anionic polymers to produce complex-
coacervate phases is a subject of fundamental importance to colloid and polymer science as …
coacervate phases is a subject of fundamental importance to colloid and polymer science as …
Molecular connectivity and correlation effects on polymer coacervation
Our ability to predict the thermodynamic phase behavior of a material system is a direct
reflection on our understanding of the relevant interactions. Voorn–Overbeek (VO) theory …
reflection on our understanding of the relevant interactions. Voorn–Overbeek (VO) theory …
Molecular design of self-coacervation phenomena in block polyampholytes
Coacervation is a common phenomenon in natural polymers and has been applied to
synthetic materials systems for coatings, adhesives, and encapsulants. Single-component …
synthetic materials systems for coatings, adhesives, and encapsulants. Single-component …
Prism-based theory of complex coacervation: Excluded volume versus chain correlation
Aqueous solutions of oppositely charged polyelectrolytes can undergo liquid–liquid phase
separation into materials known as complex coacervates. These coacervates have been a …
separation into materials known as complex coacervates. These coacervates have been a …