Infrared plastic optics and photonic devices using chalcogenide hybrid inorganic/organic polymers via inverse vulcanization of elemental sulfur
Since the invention of inverse vulcanization and high sulfur content polymers, termed
Chalcogenide Hybrid Inorganic/Organic Polymers, the application of these polymers as …
Chalcogenide Hybrid Inorganic/Organic Polymers, the application of these polymers as …
A decade development of inverse vulcanization towards green and sustainable practices
H Shen, B Zheng, H Zhang - Polymer Reviews, 2024 - Taylor & Francis
Inverse vulcanization utilizes alkenyl monomers and elemental sulfur, an excessive by-
product of oil and gas refineries, to synthesize dynamically crosslinked sulfur-rich polymers …
product of oil and gas refineries, to synthesize dynamically crosslinked sulfur-rich polymers …
Structural evolution during inverse vulcanization
Inverse vulcanization exploits S8 to synthesize polysulfides. However, evolution of products
and its mechanism during inverse vulcanization remains elusive. Herein, inverse …
and its mechanism during inverse vulcanization remains elusive. Herein, inverse …
Nanoscale 0D/1D Heterojunction of MAPbBr3/COF Toward Efficient LED-Driven S–S Coupling Reactions
Y Wang, H Li, Q Lin, J Zhao, X Fang, N Wen… - ACS …, 2023 - ACS Publications
Precise and efficient management of disulfide bonds will offer multiple merits for the
development of organosulfur chemistry, pharmacology, and life sciences. However, the …
development of organosulfur chemistry, pharmacology, and life sciences. However, the …
Unraveling the rheology of inverse vulcanized polymers
Multiple relaxation times are used to capture the numerous stress relaxation modes found in
bulk polymer melts. Herein, inverse vulcanization is used to synthesize high sulfur content …
bulk polymer melts. Herein, inverse vulcanization is used to synthesize high sulfur content …
Synthesis of deuterated and sulfurated polymers by inverse vulcanization: engineering infrared transparency via deuteration
The synthesis of deuterated, sulfurated, proton-free, glassy polymers offers a route to optical
polymers for infrared (IR) optics, specifically for midwave IR (MWIR) photonic devices …
polymers for infrared (IR) optics, specifically for midwave IR (MWIR) photonic devices …
Synthesis of Polycyclic Olefinic Monomers from Norbornadiene for Inverse Vulcanization: Structural and Mechanistic Consequences
The preparation of high-sulfur content organosulfur polymers has generated considerable
interest as an emerging area in polymer science that has been driven by advances in the …
interest as an emerging area in polymer science that has been driven by advances in the …
Ring‐Opening Terpolymerisation of Elemental Sulfur Waste with Propylene Oxide and Carbon Disulfide via Lithium Catalysis
C Gallizioli, D Battke, H Schlaad… - Angewandte …, 2024 - Wiley Online Library
Elemental sulfur, a waste product of the oil refinement process, represents a promising raw
material for the synthesis of degradable polymers. We show that simple lithium alkoxides …
material for the synthesis of degradable polymers. We show that simple lithium alkoxides …
Designing Strategy for High Refractive Index Polymers: From the Molecular Level to Bulk Structure Control
High refractive index polymers (HRIPs) are essential materials for many optical applications,
including organic light-emitting diodes (OLEDs), charge-coupled devices (CCDs) …
including organic light-emitting diodes (OLEDs), charge-coupled devices (CCDs) …
Manipulating Inverse Vulcanization Comonomers to Generate High-Tensile-Strain Polymers
The buildup of waste sulfur poses issues of storage and usage that may be prevented by the
development of high-sulfur-content functional materials. Inverse vulcanization allows for the …
development of high-sulfur-content functional materials. Inverse vulcanization allows for the …