Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts
GC Vougioukalakis, RH Grubbs - Chemical reviews, 2010 - ACS Publications
The fascinating story of olefin (or alkene) metathesis (eq 1) began almost five decades ago,
when Anderson and Merckling reported the first carbonrcarbon double-bond rearrangement …
when Anderson and Merckling reported the first carbonrcarbon double-bond rearrangement …
Equilibrium ring-closing metathesis
Ring-closing metathesis (RCM) of dienes is one of the most important methodologies now in
use for the assembly of cyclic organic compounds. First employed by Villemin and by Tsuji …
use for the assembly of cyclic organic compounds. First employed by Villemin and by Tsuji …
[BOOK][B] Handbook of Metathesis, Volume 2: Applications in Organic Synthesis
RH Grubbs, DJ O'Leary - 2015 - books.google.com
The second edition of the" go-to" reference in this field is completely updated and features
more than 80% new content, with emphasis on new developments in the field, especially in …
more than 80% new content, with emphasis on new developments in the field, especially in …
Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis
Several new C–H-activated ruthenium catalysts for Z-selective olefin metathesis have been
synthesized. Both the carboxylate ligand and the aryl group of the N-heterocyclic carbene …
synthesized. Both the carboxylate ligand and the aryl group of the N-heterocyclic carbene …
Olefin metathesis: what have we learned about homogeneous and heterogeneous catalysts from surface organometallic chemistry?
Since its early days, olefin metathesis has been in the focus of scientific discussions and
technology development. While heterogeneous olefin metathesis catalysts based on …
technology development. While heterogeneous olefin metathesis catalysts based on …
New bonding modes of carbon and heavier group 14 atoms Si–Pb
G Frenking, R Tonner, S Klein, N Takagi… - Chemical Society …, 2014 - pubs.rsc.org
Recent theoretical studies are reviewed which show that the naked group 14 atoms E= C–
Pb in the singlet 1D state behave as bidentate Lewis acids that strongly bind two σ donor …
Pb in the singlet 1D state behave as bidentate Lewis acids that strongly bind two σ donor …
Carbon-13 NMR chemical shift: a descriptor for electronic structure and reactivity of organometallic compounds
Conspectus Metal-bonded carbon atoms in metal–alkyl, metal–carbene/alkylidene, and
metal–carbyne/alkylidyne species often show significantly more deshielded isotropic …
metal–carbyne/alkylidyne species often show significantly more deshielded isotropic …
Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity
AH Hoveyda - The Journal of organic chemistry, 2014 - ACS Publications
There have been numerous significant advances in catalytic olefin metathesis (OM) during
the past two decades. Such progress has transformed this important set of reactions to …
the past two decades. Such progress has transformed this important set of reactions to …
Readily Accessible and Easily Modifiable Ru-Based Catalysts for Efficient and Z-Selective Ring-Opening Metathesis Polymerization and Ring-Opening/Cross …
RKM Khan, S Torker, AH Hoveyda - Journal of the American …, 2013 - ACS Publications
Rationally designed Ru-based catalysts for efficient Z-selective olefin metathesis are
featured. The new complexes contain a dithiolate ligand and can be accessed in a single …
featured. The new complexes contain a dithiolate ligand and can be accessed in a single …
Key processes in ruthenium-catalysed olefin metathesis
While the fundamental series of [2+ 2] cycloadditions and retro [2+ 2] cycloadditions that
make up the pathways of ruthenium-catalysed metathesis reactions is well-established, the …
make up the pathways of ruthenium-catalysed metathesis reactions is well-established, the …