Beyond charge balance: counter‐cations in polyoxometalate chemistry

A Misra, K Kozma, C Streb… - Angewandte Chemie …, 2020 - Wiley Online Library
Polyoxometalates (POMs) are molecular metal‐oxide anions applied in energy conversion
and storage, manipulation of biomolecules, catalysis, as well as materials design and …

Exploiting interactions between polyoxometalates and proteins for applications in (bio) chemistry and medicine

S Lentink, DE Salazar Marcano… - Angewandte …, 2023 - Wiley Online Library
The specific interactions of anionic metal‐oxo clusters, known as polyoxometalates (POMs),
with proteins can be leveraged for a wide range of analytical and biomedical applications …

The novel application of polyoxometalates for achieving sludge deep dewatering using low-temperature thermal hydrolysis pretreatment

X Ling, H Zheng, J Huang, H Sun, S Xu, H Zeng… - Journal of cleaner …, 2024 - Elsevier
Traditional thermal hydrolysis pretreatment (THP) for sludge deep dewatering is energy-
intensive and poses the risk of generating bio-toxic substances that affect downstream …

Molecular Insights into Sequence-Specific Protein Hydrolysis by a Soluble Zirconium-Oxo Cluster Catalyst

K Declerck, ND Savić, MA Moussawi… - Journal of the …, 2024 - ACS Publications
The development of catalysts for controlled fragmentation of proteins is a critical undertaking
in modern proteomics and biotechnology.{Zr6O8}-based metal–organic frameworks (MOFs) …

Exploring the reactivity of polyoxometalates toward proteins: from interactions to mechanistic insights

DE Salazar Marcano, ND Savić, SAM Abdelhameed… - JACS Au, 2023 - ACS Publications
The latest advances in the study of the reactivity of metal-oxo clusters toward proteins
showcase how fundamental insights obtained so far open new opportunities in …

The dawn of metal-oxo clusters as artificial proteases: from discovery to the present and beyond

F Azambuja, J Moons… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus The selective cleavage of peptide bonds in proteins is of paramount importance
in many areas of the biological and medical sciences, playing a key role in protein …

Polyoxometalate–peptide hybrid materials: from structure–property relationships to applications

H Soria-Carrera, E Atrián-Blasco, R Martín-Rapún… - Chemical …, 2023 - pubs.rsc.org
Organo-functionalisation of polyoxometalates (POMs) represents an effective approach to
obtain diverse arrays of functional structures and materials, where the introduction of organic …

Interactions between polyoxometalates and biological systems: from drug design to artificial enzymes

LS Van Rompuy, TN Parac-Vogt - Current opinion in biotechnology, 2019 - Elsevier
Polyoxometalates have long been studied in a variety of biological applications. Interactions
between the highly charged POM molecules and biological molecules frequently occur …

Nonconventional three-component hierarchical host–guest assembly based on Mo-blue ring-shaped giant anion, γ-cyclodextrin, and Dawson-type polyoxometalate

MA Moussawi, M Haouas, S Floquet… - Journal of the …, 2017 - ACS Publications
In this communication, we report on a noteworthy hybrid supramolecular assembly built from
three functional components hierarchically organized through noncovalent interactions. The …

Polyoxometalates: more than a phasing tool in protein crystallography

A Bijelic, A Rompel - ChemTexts, 2018 - Springer
Protein crystallography is the most widely used method for determining the molecular
structure of proteins and obtaining structural information on protein–ligand complexes at the …