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Unveiling an indole alkaloid diketopiperazine biosynthetic pathway that features a unique stereoisomerase and multifunctional methyltransferase
G Deletti, SD Green, C Weber, KN Patterson… - Nature …, 2023 - nature.com
Abstract The 2, 5-diketopiperazines are a prominent class of bioactive molecules. The
nocardioazines are actinomycete natural products that feature a pyrroloindoline …
nocardioazines are actinomycete natural products that feature a pyrroloindoline …
Production of Diketopiperazine Derivatives by Pathway Engineering with Different Cyclodipeptide Synthases from Various Streptomyces Strains
SA Stierle, L Harken, SM Li - ACS Synthetic Biology, 2023 - ACS Publications
Cyclodipeptides from fungi and bacteria are often modified by different tailoring enzymes.
They display various biological and pharmacological activities, and some derivatives are …
They display various biological and pharmacological activities, and some derivatives are …
A nucleobase-driven P450 peroxidase system enables regio-and stereo-specific formation of C─ C and C─ N bonds
G Wei, B Duan, TP Zhou, W Tian, C Sun, Z Lin… - Proceedings of the …, 2024 - pnas.org
P450 peroxidase activities are valued for their ability to catalyze complex chemical
transformations using economical H2O2; however, they have been largely underexplored …
transformations using economical H2O2; however, they have been largely underexplored …
Divergent Metabolism of Cyclo-l-Trp-l-Leu in Streptomyces albofaciens by Hydroxylation and Nucleobase Transfer with Two Cytochrome P450 Enzymes
Y Dai, D Ostendorff, SM Li - Journal of Natural Products, 2024 - ACS Publications
A three-gene salb cluster from Streptomyces albofaciens was proven to be responsible for
the formation of cyclo-l-Trp-l-Leu (cWL) derivatives. An Escherichia coli strain harboring the …
the formation of cyclo-l-Trp-l-Leu (cWL) derivatives. An Escherichia coli strain harboring the …
Intramolecular Coupling and Nucleobase Transfer – How Cytochrome P450 Enzymes GymBx Establish Their Chemoselectivity
Cyclodipeptides (CDPs) build an important class of secondary metabolites with a plethora of
pharmacological impact such as antibiotic, cytotoxic, antifungal properties or even as anti …
pharmacological impact such as antibiotic, cytotoxic, antifungal properties or even as anti …
P450 in C–C coupling of cyclodipeptides with nucleobases
SA Stierle, L Harken, SM Li - Methods in Enzymology, 2023 - books.google.com
Bacterial cytochrome P450 enzymes catalyze various and often intriguing tailoring reactions
during the biosynthesis of natural products. In contrast to the majority of membrane-bound …
during the biosynthesis of natural products. In contrast to the majority of membrane-bound …