A review on energy band‐gap engineering for perovskite photovoltaics
Metal halide perovskites are attractive for highly efficient solar cells. As most perovskites
suffer large or indirect bandgap compared with the ideal bandgap range for single‐junction …
suffer large or indirect bandgap compared with the ideal bandgap range for single‐junction …
An Overview of Lead, Tin, and Mixed Tin–Lead‐Based ABI3 Perovskite Solar Cells
Over a short period of approximately 10 years, metal‐halide‐perovskite‐based photovoltaics
have demonstrated unprecedented improvements in solar cell performance beyond the …
have demonstrated unprecedented improvements in solar cell performance beyond the …
Illumination durability and high-efficiency Sn-based perovskite solar cell under coordinated control of phenylhydrazine and halogen ions
The organic-inorganic hybrid Sn-based perovskite has attracted extensive attention because
of its more suitable band gap and environmentally friendly characteristics, but the natural …
of its more suitable band gap and environmentally friendly characteristics, but the natural …
Microscopic degradation in formamidinium-cesium lead iodide perovskite solar cells under operational stressors
The most important obstacle to widespread use of perovskite solar cells is their poor stability
under operational stressors. Here, we systematically monitor the evolution of the …
under operational stressors. Here, we systematically monitor the evolution of the …
Negligible ion migration in tin‐based and tin‐doped perovskites
Ion migration is a notorious phenomenon observed in ionic perovskite materials. It causes
several severe issues in perovskite optoelectronic devices such as instability, current …
several severe issues in perovskite optoelectronic devices such as instability, current …
Polymorphous nature of cubic halide perovskites
Many common crystal structures can be described by a single (or very few) repeated
structural motif (“monomorphous structures”) such as octahedron in cubic halide perovskites …
structural motif (“monomorphous structures”) such as octahedron in cubic halide perovskites …
Unified theory for light-induced halide segregation in mixed halide perovskites
Mixed halide perovskites that are thermodynamically stable in the dark demix under
illumination. This is problematic for their application in solar cells. We present a unified …
illumination. This is problematic for their application in solar cells. We present a unified …
Light‐Induced Frenkel Defect Pair Formation Can Lead to Phase‐Segregation of Otherwise Miscible Halide Perovskite Alloys
Alloys of ABX3 halide perovskites (HP) exhibit unique phase behavior compared to
traditional III‐V and II‐VI semiconductor alloys used in solar cells. While the latter typically …
traditional III‐V and II‐VI semiconductor alloys used in solar cells. While the latter typically …
Suppressing cation migration in triple-cation lead halide perovskites
Ion migration represents an intrinsic instability of metal halide perovskite solar cells. Here we
show that triple-cation FA x MA y Cs1–x–y PbI3 [FA+=(NH2) 2CH+, MA+= CH3NH3+] active …
show that triple-cation FA x MA y Cs1–x–y PbI3 [FA+=(NH2) 2CH+, MA+= CH3NH3+] active …
Effect of static local distortions vs. dynamic motions on the stability and band gaps of cubic oxide and halide perovskites
Ternary ABX 3 perovskites made of corner-sharing BX 6 octahedra have long featured
prominently in solid-state chemistry and condensed matter physics. Still, the joint …
prominently in solid-state chemistry and condensed matter physics. Still, the joint …