A review on energy band‐gap engineering for perovskite photovoltaics

Z Hu, Z Lin, J Su, J Zhang, J Chang, Y Hao - Solar Rrl, 2019 - Wiley Online Library
Metal halide perovskites are attractive for highly efficient solar cells. As most perovskites
suffer large or indirect bandgap compared with the ideal bandgap range for single‐junction …

An Overview of Lead, Tin, and Mixed Tin–Lead‐Based ABI3 Perovskite Solar Cells

J Seo, T Song, S Rasool, S Park… - Advanced Energy and …, 2023 - Wiley Online Library
Over a short period of approximately 10 years, metal‐halide‐perovskite‐based photovoltaics
have demonstrated unprecedented improvements in solar cell performance beyond the …

Illumination durability and high-efficiency Sn-based perovskite solar cell under coordinated control of phenylhydrazine and halogen ions

C Wang, Y Zhang, F Gu, Z Zhao, H Li, H Jiang, Z Bian… - Matter, 2021 - cell.com
The organic-inorganic hybrid Sn-based perovskite has attracted extensive attention because
of its more suitable band gap and environmentally friendly characteristics, but the natural …

Microscopic degradation in formamidinium-cesium lead iodide perovskite solar cells under operational stressors

N Li, Y Luo, Z Chen, X Niu, X Zhang, J Lu, R Kumar… - Joule, 2020 - cell.com
The most important obstacle to widespread use of perovskite solar cells is their poor stability
under operational stressors. Here, we systematically monitor the evolution of the …

Negligible ion migration in tin‐based and tin‐doped perovskites

KO Ighodalo, W Chen, Z Liang, Y Shi… - Angewandte Chemie …, 2023 - Wiley Online Library
Ion migration is a notorious phenomenon observed in ionic perovskite materials. It causes
several severe issues in perovskite optoelectronic devices such as instability, current …

Polymorphous nature of cubic halide perovskites

XG Zhao, GM Dalpian, Z Wang, A Zunger - Physical Review B, 2020 - APS
Many common crystal structures can be described by a single (or very few) repeated
structural motif (“monomorphous structures”) such as octahedron in cubic halide perovskites …

Unified theory for light-induced halide segregation in mixed halide perovskites

Z Chen, G Brocks, S Tao, PA Bobbert - Nature communications, 2021 - nature.com
Mixed halide perovskites that are thermodynamically stable in the dark demix under
illumination. This is problematic for their application in solar cells. We present a unified …

Light‐Induced Frenkel Defect Pair Formation Can Lead to Phase‐Segregation of Otherwise Miscible Halide Perovskite Alloys

FP Sabino, GM Dalpian… - Advanced Energy Materials, 2023 - Wiley Online Library
Alloys of ABX3 halide perovskites (HP) exhibit unique phase behavior compared to
traditional III‐V and II‐VI semiconductor alloys used in solar cells. While the latter typically …

Suppressing cation migration in triple-cation lead halide perovskites

IM Pavlovetc, MC Brennan, S Draguta, A Ruth… - ACS Energy …, 2020 - ACS Publications
Ion migration represents an intrinsic instability of metal halide perovskite solar cells. Here we
show that triple-cation FA x MA y Cs1–x–y PbI3 [FA+=(NH2) 2CH+, MA+= CH3NH3+] active …

Effect of static local distortions vs. dynamic motions on the stability and band gaps of cubic oxide and halide perovskites

XG Zhao, Z Wang, OI Malyi, A Zunger - Materials Today, 2021 - Elsevier
Ternary ABX 3 perovskites made of corner-sharing BX 6 octahedra have long featured
prominently in solid-state chemistry and condensed matter physics. Still, the joint …