Recent advances in the rational designing of metalloporphyrinoid-based reduction catalysts: From molecular structural tuning to the application in catalysis

B Domingo-Tafalla, T Chatterjee… - Journal of Porphyrins …, 2023 - World Scientific
Electro and photochemical CO 2 reduction (CO 2 R) has emerged as a contemporary
research field for tackling the fossil fuel problems and construction of a modern chemical …

Photocatalytic CO2 reduction by Ni-substituted polyoxometalates: Structure-activity relationships and mechanistic insights

K Talbi, F Penas-Hidalgo, AL Robinson… - Applied Catalysis B …, 2024 - Elsevier
The photocatalytic activity for CO 2 reduction of a series of Ni-substituted polyoxometalates
(POMs) differing in nuclearity, shape and size, has been investigated under visible light …

Bichromophoric Photosensitizers: How and Where to Attach Pyrene Moieties to Phenanthroline to Generate Copper (I) Complexes

F Doettinger, Y Yang, M Karnahl… - Inorganic Chemistry, 2023 - ACS Publications
Pyrene is a polycyclic aromatic hydrocarbon and organic dye that can form superior
bichromophoric systems when combined with a transition metal-based chromophore …

Electron-rich active sites created by fine-tuning the electronic structure of Co (II) porphyrin frameworks for high-performance CO2 electroreduction

Q He, S Huang, H Li, TT Li - International Journal of Hydrogen Energy, 2024 - Elsevier
Electrochemical reduction of CO 2 for sustainable production of carbon-based chemicals
and fuels is a promising approach to solve environmental and energy problems. However …

Selective Photocatalytic Reduction of Acetylene to Ethylene Powered by a Cobalt-Porphyrin Metal–Organic Framework

AEBS Stone, L Đord̵ević, SI Stupp, EA Weiss… - ACS Energy …, 2023 - ACS Publications
Purifying crude ethylene streams from an acetylene contaminant using state-of-the-art
thermal hydrogenation requires high temperature, an external feed of H2 gas, and noble …

Multi-Variable Multi-Metric Optimization of Self-Assembled Photocatalytic CO2 Reduction Performance Using Machine Learning Algorithms

SA Bonke, G Trezza, L Bergamasco… - Journal of the …, 2024 - ACS Publications
The sunlight-driven reduction of CO2 into fuels and platform chemicals is a promising
approach to enable a circular economy. However, established optimization approaches are …

Water-Induced Switching in Selectivity and Steric Control of Activity in Photochemical CO2 Reduction Catalyzed by RhCp*(bpy) Derivatives

D Lee, K Yamauchi, K Sakai - Journal of the American Chemical …, 2024 - ACS Publications
Photocatalytic reduction of CO2 to formic acid (HCOOH) was investigated in either organic
or aqueous/organic media by employing three water-soluble [RhIIICp*(LH2) Cl]+(LH2= n, n' …

Organic and Non‐Precious Metal Photosensitizers for Photocatalytic CO2 Reduction

Y Xue, D Chao - ChemPhotoChem, 2024 - Wiley Online Library
Carbon dioxide (CO2) is the primary greenhouse gas responsible for global warming,
posing a significant challenge to the global environment. To reduce CO2 emission and …

Efficient syngas production with controllable CO: H 2 ratios based on aqueous electrocatalytic CO 2 reduction over mesoporous TiO 2 films modified with a cobalt …

H Ozawa, R Kikunaga, H Suzuki, R Abe… - Sustainable Energy & …, 2023 - pubs.rsc.org
There is an industrial demand to develop a facile method to produce syngas having a
specific CO: H2 ratio for the sake of synthesizing various value-added chemicals. Especially …

Sewage remediation using solar energy and a triply fused Zn-porphyrin dimer molecular graphene photocatalytic agent

F Cheng, T Qiang, M Li, TD James - Catalysis Science & Technology, 2023 - pubs.rsc.org
Photocatalysis plays a pivotal role in achieving clean energy and a pollution-free
environment. However, its practical application is limited by the complexity of photoreactors …