The field of olefin polymerization catalysis has experienced a phenomenal acceleration in
research activity over the past 5 years, with many academic and industrial research …

Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

Synthetic organic chemists have scoured the depths and breadth of the periodic table in
search of novel, unique, and efficient methods to assemble small molecules. Metal …

This Review gives an overview on recent progress in the synthesis and chemistry of rare-
earth metal dialkyl complexes bearing monoanionic ancillary ligands, with an emphasis on …

Organometallic complexes of the rare-earth metals are conventionally supported by bis
(cyclopentadienyl) ligand frameworks, 1-8 in particular if such complexes are used as …

This review describes recent advances in the synthesis and polymerization chemistry of
organolanthanide complexes (including those of scandium and yttrium), with emphasis …

A series of new alkoxy‐amino‐bis (phenols)(H2L 1–6) has been synthesized by Mannich
condensations of substituted phenols, formaldehyde, and amino ethers or diamines. The …

The past decade has witnessed an enormous growth in the chemistry of σ-bonded rare-
earth metal (Ln) alkyls, particularly due to their relevance for Ziegler-type anionic …

Over the past decade, several groups have targeted well-defined organometallic Group 3
metal complexes with ancillary ligand supporting environments alternative to the ubiquitous …

On treatment with 1 equiv of [Ph3C][B (C6F5) 4], the scandium half-sandwich bis (alkyl)
complex (C5Me4SiMe3) Sc (CH2SiMe3) 2 (THF) showed extremely high activity (up to …