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Progress in phenanthroline-derived extractants for trivalent actinides and lanthanides separation: where to next?
X Yang, L Xu, D Fang, A Zhang, C **ao - Chemical Communications, 2024 - pubs.rsc.org
Spent nuclear fuel (SNF) released from reactors possesses significant radioactivity, heat
release properties, and high-value radioactive nuclides. Therefore, using chemical methods …
release properties, and high-value radioactive nuclides. Therefore, using chemical methods …
Nonaqueous Electrochemistry of Uranium Complexes: A Guide to Structure–Reactivity Tuning
J Riedhammer, DP Halter, K Meyer - Chemical Reviews, 2023 - ACS Publications
Uranium complexes can be stabilized in a wide range of oxidation states, ranging from UII to
UVI and a very recent example of a UI complex. This review provides a comprehensive …
UVI and a very recent example of a UI complex. This review provides a comprehensive …
A Supported Pd2 Dual‐Atom Site Catalyst for Efficient Electrochemical CO2 Reduction
Dual‐atom site catalysts (DACs) have emerged as a new frontier in heterogeneous catalysis
because the synergistic effect between adjacent metal atoms can promote their catalytic …
because the synergistic effect between adjacent metal atoms can promote their catalytic …
High Flux and Stability of Cationic Intercalation in Transition-Metal Oxides: Unleashing the Potential of Mn t2g Orbital via Enhanced π-Donation
S Yao, S Wang, Y Liu, Z Hou, J Wang… - Journal of the …, 2023 - ACS Publications
Transition-metal oxides (TMOs) often struggle with challenges related to low electronic
conductivity and unsatisfactory cyclic stability toward cationic intercalation. In this work, we …
conductivity and unsatisfactory cyclic stability toward cationic intercalation. In this work, we …
N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners
Comparison of bonding and electronic structural features between trivalent lanthanide (Ln)
and actinide (An) complexes across homologous series' of molecules can provide insights …
and actinide (An) complexes across homologous series' of molecules can provide insights …
Architector for high-throughput cross-periodic table 3D complex building
Rare-earth and actinide complexes are critical for a wealth of clean-energy applications.
Three-dimensional (3D) structural generation and prediction for these organometallic …
Three-dimensional (3D) structural generation and prediction for these organometallic …
31P Nuclear Magnetic Resonance Spectroscopy as a Probe of Thorium–Phosphorus Bond Covalency: Correlating Phosphorus Chemical Shift to Metal–Phosphorus …
We report the use of solution and solid-state 31P Nuclear Magnetic Resonance (NMR)
spectroscopy combined with Density Functional Theory calculations to benchmark the …
spectroscopy combined with Density Functional Theory calculations to benchmark the …
Progress in Nonaqueous Molecular Uranium Chemistry: Where to Next?
ST Liddle - Inorganic Chemistry, 2024 - ACS Publications
There is long-standing interest in nonaqueous uranium chemistry because of fundamental
questions about uranium's variable chemical bonding and the similarities of this pseudo …
questions about uranium's variable chemical bonding and the similarities of this pseudo …
5f Covalency Synergistically Boosting Oxygen Evolution of UCoO4 Catalyst
Electronic structure modulation among multiple metal sites is key to the design of efficient
catalysts. Most studies have focused on regulating 3d transition-metal active ions through …
catalysts. Most studies have focused on regulating 3d transition-metal active ions through …
Investigation of f-element interactions with functionalized diamides of phenanthroline-based ligands
Separations relevant to trivalent actinides and lanthanides have been a focus of the f-
element community in the past few decades. A central focus of this effort has been …
element community in the past few decades. A central focus of this effort has been …