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Cross-link density estimation of PDMS networks with precise consideration of networks defects
Two series of randomly cross-linked poly (dimethylsiloxane)(PDMS) networks with
systematically varying and well-defined dangling chain and defect content were investigated …
systematically varying and well-defined dangling chain and defect content were investigated …
Inhomogeneities and chain dynamics in diene rubbers vulcanized with different cure systems
JL Valentín, P Posadas, A Fernández-Torres… - …, 2010 - ACS Publications
In this study, we focus on qualitative differences in the network structure and dynamics of
natural as well as poly (butadiene) rubber in dependence of the cure system …
natural as well as poly (butadiene) rubber in dependence of the cure system …
Research on architecture and composition of natural network in natural rubber
C Huang, G Huang, S Li, M Luo, H Liu, X Fu, W Qu… - Polymer, 2018 - Elsevier
Though the superior properties of natural rubber (NR) have been attributed to its special
network architecture, the currently accepted model “naturally occurring network” is far from …
network architecture, the currently accepted model “naturally occurring network” is far from …
New insight into structure-property relationships of natural rubber and styrene-butadiene rubber nanocomposites filled with MWCNT
P Bernal-Ortega, MM Bernal, A González-Jiménez… - Polymer, 2020 - Elsevier
The outstanding properties of carbon nanotubes (CNT) have generated a lot of interest at a
scientist and industrial level. CNT have attracted great attention due to their exceptional …
scientist and industrial level. CNT have attracted great attention due to their exceptional …
Looking over liquid silicone rubbers:(2) mechanical properties vs network topology
E Delebecq, N Hermeline, A Flers… - ACS applied materials …, 2012 - ACS Publications
In the previous paper of this series, eight formulations were analyzed under their uncross-
linked forms to relate liquid silicone rubber (LSR) chemical compositions to material network …
linked forms to relate liquid silicone rubber (LSR) chemical compositions to material network …
Water swelling behavior of poly (ethylene glycol)-based polyurethane networks
PTM Albers, LGJ van der Ven… - …, 2020 - ACS Publications
Defects in a polymer network complicate an accurate calculation of structural parameters
such as the molar mass between cross-links M c, typically obtained from experimental …
such as the molar mass between cross-links M c, typically obtained from experimental …
Influence of the vulcanization system on the dynamics and structure of natural rubber: Comparative study by means of broadband dielectric spectroscopy and solid …
A study on the effects of the curing systems on the dynamics and network structure of Natural
rubber (NR) is performed by using broadband dielectric spectroscopy (BDS) and proton …
rubber (NR) is performed by using broadband dielectric spectroscopy (BDS) and proton …
Contribution of entanglements to polymer network elasticity
Trapped entanglements, cross-linker functionality, and elastically effective chains are the
sources of elasticity of polymer networks and gels. However, despite more than 80 years of …
sources of elasticity of polymer networks and gels. However, despite more than 80 years of …
Water Confined in Mesoporous TiO2 Aerosols: Insights from NMR Experiments and Molecular Dynamics Simulations
The adsorption of water vapor in mesoporous TiO2 was studied by nuclear magnetic
resonance (NMR) and multiscale molecular dynamics simulations. Three different water …
resonance (NMR) and multiscale molecular dynamics simulations. Three different water …
Particle-induced network formation in linear PDMS filled with silica
A Şerbescu, K Saalwächter - Polymer, 2009 - Elsevier
We study the formation of permanent elastomers from linear PDMS chains by solution
blending with up to 25wt% fumed silica. The physical networks are characterized by time …
blending with up to 25wt% fumed silica. The physical networks are characterized by time …