Two‐Electron Redox Reactivity of Thorium Supported by Redox‐Active Tripodal Frameworks
The high stability of the+ IVoxidation state limits thorium redox reactivity. Here we report the
synthesis and the redox reactivity of two Th (IV) complexes supported by the arene‐tethered …
synthesis and the redox reactivity of two Th (IV) complexes supported by the arene‐tethered …
The role of 5f-orbital participation in unexpected inversion of the σ-bond metathesis reactivity trend of triamidoamine thorium (IV) and uranium (IV) alkyls
We report on the role of 5f-orbital participation in the unexpected inversion of the σ-bond
metathesis reactivity trend of triamidoamine thorium (IV) and uranium (IV) alkyls. Reaction of …
metathesis reactivity trend of triamidoamine thorium (IV) and uranium (IV) alkyls. Reaction of …
Investigations of the electronic structure of arene-bridged diuranium complexes
The electronic structure of the arene-bridged complex (μ-toluene) U2 (N [tBu] Ar) 4 (1a 2-μ-
toluene, Ar= 3, 5-C6H3Me2) has been studied in relation to a variety of mononuclear …
toluene, Ar= 3, 5-C6H3Me2) has been studied in relation to a variety of mononuclear …
Uranium (IV) alkyl cations: synthesis, structures, comparison with thorium (IV) analogues, and the influence of arene-coordination on thermal stability and ethylene …
NR Andreychuk, B Vidjayacoumar, JS Price… - Chemical …, 2022 - pubs.rsc.org
Reaction of [(XA2) U (CH2SiMe3) 2](1; XA2= 4, 5-bis (2, 6-diisopropylanilido)-2, 7-di-tert-
butyl-9, 9-dimethylxanthene) with 1 equivalent of [Ph3C][B (C6F5) 4] in arene solvents …
butyl-9, 9-dimethylxanthene) with 1 equivalent of [Ph3C][B (C6F5) 4] in arene solvents …
Mechanochemical synthesis of iron aluminyl complexes
F Kallmeier, AJR Matthews, GR Nelmes… - Dalton …, 2024 - pubs.rsc.org
A series of iron aluminyl complexes have been synthesised in good crystalline yields from
reactions between bulky diamido aluminium iodide complexes and K [Fe (CO) 2Cp] in the …
reactions between bulky diamido aluminium iodide complexes and K [Fe (CO) 2Cp] in the …
Actinide coordination and organometallic complexes with multidentate polyamido ligands
CE Hayes, DB Leznoff - Coordination Chemistry Reviews, 2014 - Elsevier
Amido-based ligand sets have found considerable use in the active and growing area of
actinide chemistry, forming highly reactive and unusual actinide-containing complexes as a …
actinide chemistry, forming highly reactive and unusual actinide-containing complexes as a …
Synthesis and Structure of (Ph4P)2MCl6 (M = Ti, Zr, Hf, Th, U, Np, Pu)
High-purity syntheses are reported for a series of first, second, and third row transition metal
and actinide hexahalide compounds with equivalent, noncoordinating …
and actinide hexahalide compounds with equivalent, noncoordinating …
Uranium(IV) Halide (F−, Cl−, Br−, and I−) Monoarene Complexes
DP Halter, HS La Pierre, FW Heinemann… - Inorganic …, 2014 - ACS Publications
The syntheses of four nearly isostructural uranium (IV) monoarene complexes, supported by
the arene anchored tris (aryloxide) chelate,[(Ad, MeArO) 3mes] 3–, are reported. Oxidation of …
the arene anchored tris (aryloxide) chelate,[(Ad, MeArO) 3mes] 3–, are reported. Oxidation of …
A thorium chalcogenolate series generated by atom insertion into thorium–carbon bonds
A new thorium monoalkyl complex, Th (CH2SiMe3)(L3)(L= MeC (N i Pr) 2)(2), undergoes
insertion of chalcogen atoms resulting in a series of thorium chalcogenolate complexes, Th …
insertion of chalcogen atoms resulting in a series of thorium chalcogenolate complexes, Th …
Switchable π-coordination and C–H metallation in small-cavity macrocyclic uranium and thorium complexes
New, conformationally restricted ThIV and UIV complexes,[ThCl2 (L)] and [UI2 (L)], of the
small-cavity, dipyrrolide, dianionic macrocycle trans-calix [2] benzene [2] pyrrolide (L) 2− are …
small-cavity, dipyrrolide, dianionic macrocycle trans-calix [2] benzene [2] pyrrolide (L) 2− are …