[HTML][HTML] Fluid-mediated element cycling in subducted oceanic lithosphere: The orogenic serpentinite perspective

T Pettke, A Bretscher - Earth-Science Reviews, 2022 - Elsevier
Serpentinites are central to water (re) cycling in subduction zones and thus effect fluid-
mediated element transfer between the hydrosphere and the Earth's mantle and back into …

Uncovering and quantifying the subduction zone sulfur cycle from the slab perspective

JL Li, EM Schwarzenbach, T John, JJ Ague… - Nature …, 2020 - nature.com
Sulfur belongs among H2O, CO2, and Cl as one of the key volatiles in Earth's chemical
cycles. High oxygen fugacity, sulfur concentration, and δ34S values in volcanic arc rocks …

Slab-derived devolatilization fluids oxidized by subducted metasedimentary rocks

JJ Ague, S Tassara, ME Holycross, JL Li, E Cottrell… - Nature …, 2022 - nature.com
Metamorphic devolatilization of subducted slabs generates aqueous fluids that ascend into
the mantle wedge, driving the partial melting that produces arc magmas. These magmas …

Subducting serpentinites release reduced, not oxidized, aqueous fluids

F Piccoli, J Hermann, T Pettke, JAD Connolly… - Scientific Reports, 2019 - nature.com
The observation that primitive arc magmas are more oxidized than mid-ocean-ridge basalts
has led to the paradigm that slab-derived fluids carry SO2 and CO2 that metasomatize and …

High-pressure synthesis and storage of solid organic compounds in active subduction zones

B Debret, B Ménez, B Walter, H Bouquerel… - Science …, 2022 - science.org
Recent thermodynamic and experimental studies have suggested that volatile organic
compounds (eg, methane, formate, and acetate) can be produced and stabilized in …

Deserpentinization in subduction zones as a source of oxidation in arcs: A reality check

KA Evans, BR Frost - Journal of Petrology, 2020 - ieeexplore.ieee.org
Previous studies have concluded that dehydration of serpentinites in subduction zones
produces oxidizing fluids that are the cause of oxidized arc magmas. Here, observations of …

Sulfur disproportionation in deep COHS slab fluids drives mantle wedge oxidation

A Maffeis, ML Frezzotti, JAD Connolly, D Castelli… - Science …, 2024 - science.org
Sulfur degassed at volcanic arcs calls for dissolved sulfate ions (S6+) released by
subduction-zone fluids, oxidizing (in association with carbon) the subarc mantle, but sulfur …

Fluid-mediated carbon release from serpentinite-hosted carbonates during dehydration of antigorite-serpentinite in subduction zones

MD Menzel, CJ Garrido… - Earth and Planetary …, 2020 - Elsevier
Subduction of serpentinite-hosted carbonate rocks formed during the oceanic stage in the
oceanic lithosphere (ophicalcite) or by metasomatism at the slab mantle-wedge interface …

Insight into the early exhumation of the Cycladic Blueschist Unit, Syros, Greece: Combined application of zoned garnet geochronology, thermodynamic modeling, and …

JS Gorce, MJ Caddick, EF Baxter… - Geochemistry …, 2021 - Wiley Online Library
Constraining conditions and mechanisms of the early stages of exhumation from within
subduction zones is challenging. Although pressure, temperature, and age can be inferred …