Anion− π interactions with fluoroarenes

M Giese, M Albrecht, K Rissanen - Chemical Reviews, 2015 - ACS Publications
Well-orchestrated noncovalent interactions are fundamental in chemical processes. 1 For
example, the assembly of complementary subunits to form functional aggregates is a …

Synthetic ion transporters that work with anion− π interactions, halogen bonds, and anion–macrodipole interactions

A Vargas Jentzsch, A Hennig, J Mareda… - Accounts of Chemical …, 2013 - ACS Publications
The transport of ions and molecules across lipid bilayer membranes connects cells and
cellular compartments with their environment. This biological process is central to a host of …

[PDF][PDF] Catalysis with anion–π interactions

Y Zhao, Y Domoto, E Orentas, C Beuchat… - Angewandte …, 2013 - researchgate.net
The expansion of the number of intermolecular interactions available to create molecular
functional systems is of paramount importance. Quite recently, we have identified synthetic …

Enolate chemistry with anion–π interactions

Y Zhao, N Sakai, S Matile - Nature communications, 2014 - nature.com
Anion–π interactions occur on the surface of π-acidic aromatic planes with positive
quadrupole moments. Their ability to contribute to the binding and transport of anions has …

Anion‐π Interaction for Molecular Recognition of Anions: Focus on Cooperativity with Hydrogen Bonding

R Plais, G Clavier, J Salpin… - European Journal of …, 2023 - Wiley Online Library
Anion recognition represents an active area of research in supramolecular chemistry. The
last two decades have been marked by spectacular advances in the design of new anion …

The pentafluorophenyl group as π-acceptor for anions: a case study

M Giese, M Albrecht, A Valkonen, K Rissanen - Chemical Science, 2015 - pubs.rsc.org
The present study gives a comprehensive insight into anion–π interactions in the solid state,
focusing on purely organic and charge-neutral fluorophenyl groups bearing a positive …

CF3: An Electron‐Withdrawing Substituent for Aromatic Anion Acceptors? “Side‐On” versus “On‐Top” Binding of Halides

M Albrecht, H Yi, O Köksal, G Raabe… - … A European Journal, 2016 - Wiley Online Library
The ability of multiple CF3‐substituted arenes to act as acceptors for anions is investigated.
The results of quantum‐chemical calculations show that a high degree of trifluoromethyl …

[PDF][PDF] The binding behavior of fluorinated π-receptors with anions and other aromatics

H Yi - 2015 - core.ac.uk
In 2002, an unprecedented and counterintuitive concept, namely “anion-π interactions”, was
described by Pere M. Deyà and Antonio Frontera etc.. With quantum chemistry calculation of …

[PDF][PDF] Quinoline-based anion receptors and anion-pi interactions

Z Sun - 2013 - core.ac.uk
Supramolecular chemistry is defined as―the chemistry beyond the molecule‖
and―chemistry of molecular assemblies and of the intermolecular bond‖ by Jean-Marie …