Recent advances in externally controlled ring-opening polymerisations
S Kaler, MD Jones - Dalton Transactions, 2022 - pubs.rsc.org
Switchable catalysis is a powerful tool in the polymer chemist's toolbox as it allows on
demand access to a variety of polymer architectures. Switchable catalysts operate by the …
demand access to a variety of polymer architectures. Switchable catalysts operate by the …
Self-switchable polymerization: a smart approach to sequence-controlled degradable copolymers
C Hu, X Pang, X Chen - Macromolecules, 2022 - ACS Publications
In the quest for sustainable development, degradable polymers are attractive alternatives to
traditional fossil-based plastics. As monocomponent degradable polymers often suffer from …
traditional fossil-based plastics. As monocomponent degradable polymers often suffer from …
Xylan plastic
The increasing accumulation of plastic waste has brought serious environmental issues.
Biodegradable plastics are promising candidates to solve the problem but still remain a …
Biodegradable plastics are promising candidates to solve the problem but still remain a …
Zr (IV) Catalyst for the Ring-Opening Copolymerization of Anhydrides (A) with Epoxides (B), Oxetane (B), and Tetrahydrofurans (C) to Make ABB-and/or ABC-Poly …
RWF Kerr, CK Williams - Journal of the American Chemical …, 2022 - ACS Publications
Poly (ester-alt-ethers) can combine beneficial ether linkage flexibility and polarity with ester
linkage hydrolysability, furnishing fully degradable polymers. Despite their promising …
linkage hydrolysability, furnishing fully degradable polymers. Despite their promising …
Recent progress and applications enabled via electrochemically triggered and controlled chain-growth polymerizations
The use of external stimuli to trigger and/or control polymer synthesis has become a
prominent research theme over the last 20 years. With the need for more sustainable …
prominent research theme over the last 20 years. With the need for more sustainable …
Heterotrinuclear Ring Opening Copolymerization Catalysis: Structure–activity Relationships
AJ Plajer, CK Williams - ACS Catalysis, 2021 - ACS Publications
Heteronuclear complexes are highly active catalysts in alternating ring opening
copolymerizations (ROCOP) of cyclohexene oxide (CHO)/carbon dioxide or CHO/phthalic …
copolymerizations (ROCOP) of cyclohexene oxide (CHO)/carbon dioxide or CHO/phthalic …
Cyclic ether and anhydride ring opening copolymerisation delivering new ABB sequences in poly (ester-alt-ethers)
RWF Kerr, AR Craze, CK Williams - Chemical Science, 2024 - pubs.rsc.org
Poly (ester-alt-ethers) are interesting as they combine the ester linkage rigidity and potential
for hydrolysis with ether linkage flexibility. This work describes a generally applicable route …
for hydrolysis with ether linkage flexibility. This work describes a generally applicable route …
Ring Opening Copolymerization of Boron-Containing Anhydride with Epoxides as a Controlled Platform to Functional Polyesters
F Vidal, S Smith, CK Williams - Journal of the American Chemical …, 2023 - ACS Publications
Boron-functionalized polymers are used in opto-electronics, biology, and medicine. Methods
to produce boron-functionalized and degradable polyesters remain exceedingly rare but …
to produce boron-functionalized and degradable polyesters remain exceedingly rare but …
Dynamics-Driven Controlled polymerization to synthesize fully renewable poly (ester–ether) s
R Wang, H Zhang, M Jiang, Z Wang, G Zhou - Macromolecules, 2021 - ACS Publications
Producing aromatic poly (ester–ether) s from completely renewable feedstocks is almost
inaccessible via existing ring-opening polymerization or melt polycondensation methods …
inaccessible via existing ring-opening polymerization or melt polycondensation methods …
Ring-Opening Co- and Terpolymerization of Epoxides, Cyclic Anhydrides, and l-Lactide Using Constrained Aluminum Inden Complexes
N Laiwattanapaisarn, A Virachotikul… - Inorganic …, 2022 - ACS Publications
Seven constrained aluminum inden complexes having different substituents and diamine
backbones were developed for the ring-opening copolymerization (ROCOP) of epoxides …
backbones were developed for the ring-opening copolymerization (ROCOP) of epoxides …