Synthetic routes to silsesquioxane-based systems as photoactive materials and their precursors

B Dudziec, P Żak, B Marciniec - Polymers, 2019 - mdpi.com
Over the past two decades, organic optoelectronic materials have been considered very
promising. The attractiveness of this group of compounds, regardless of their undisputable …

Towards the application of purely inorganic icosahedral boron clusters in emerging nanomedicine

F Teixidor, R Núñez, C Viñas - Molecules, 2023 - mdpi.com
Traditionally, drugs were obtained by extraction from medicinal plants, but more recently
also by organic synthesis. Today, medicinal chemistry continues to focus on organic …

Palladium-catalyzed selective five-fold cascade arylation of the 12-vertex monocarborane anion by B–H activation

F Lin, JL Yu, Y Shen, SQ Zhang… - Journal of the …, 2018 - ACS Publications
A series of cage penta-arylated carboranes have been synthesized by palladium-catalyzed
intermolecular coupling of the C-carboxylic acid of the monocarba-closo-dodecaborate …

Reversible Optical Data Storage via Two-Photon Micropatterning of o-Carboranes-Embedded Switchable Materials

S Abdallah, R Mhanna, J Cabrera-González… - Chemistry of …, 2023 - ACS Publications
Two-photon polymerization (2PP) constitutes a powerful light-triggered 3D
stereolithography, allowing the fabrication of micro-or nanostructures with spatially encoded …

Theoretical study on the pyrolysis process of POSS nanocomposites based on the molecular vibration frequency

Y Kim, J Choi - Polymer Degradation and Stability, 2023 - Elsevier
Identifying the factors that determine the thermal stability of polymer nanocomposites with
inorganic fillers is vital. This study investigates how the modulation of polyhedral oligomeric …

Site‐Selective Functionalization of Carboranes at the Electron‐Rich Boron Vertex: Photocatalytic B− C Coupling via a Carboranyl Cage Radical

M Chen, J Xu, D Zhao, F Sun, S Tian… - Angewandte Chemie …, 2022 - Wiley Online Library
Functionalization of carboranes in a vertex‐specific manner is a perennial challenge. Here,
we report a photocatalytic B− C coupling for the selective functionalization of carboranes at …

o-Carborane, Ferrocene, and Phthalocyanine Triad for High-Mobility Organic Field-Effect Transistors

I Nar, A Atsay, A Altındal, E Hamuryudan - Inorganic Chemistry, 2018 - ACS Publications
An unsymmetrical zinc phthalocyanine with ferrocenylcarborane linked to the
phthalocyanine ring through a phenylethynyl spacer was designed for organic field-effect …

Highly selective palladium-catalyzed one-pot, five-fold B–H/C–H cross coupling of monocarboranes with alkenes

Y Shen, K Zhang, X Liang, R Dontha, S Duttwyler - Chemical Science, 2019 - pubs.rsc.org
Palladium-catalyzed dehydrogenative B–H/C–H cross coupling of monocarborane anions
with alkenes is reported, allowing for the first time the isolation of selectively penta …

Halogenated carborane molecular ferroelectric crystals with high-temperature phase transition

W Guo, W Cheng, Y Li, Z Wei, H Cai - Inorganic Chemistry Frontiers, 2024 - pubs.rsc.org
Molecular ferroelectrics possess spontaneous polarization, finding applications in sensors,
memory devices, capacitors, among others. However, most of these materials are hybrids of …

Introducing borane clusters into polymeric frameworks: architecture, synthesis, and applications

J Yan, W Yang, Q Zhang, Y Yan - Chemical Communications, 2020 - pubs.rsc.org
Borane clusters represent a unique class of nano-objects not only because of their special
coordination and 3D structure but also due to their broad applications ranging from heat …