Critical analysis on catalytic methylcyclohexane dehydrogenation reaction: A review

X Dai, R Verma, X Zhang, J Bai, SK Verma… - International Journal of …, 2024 - Elsevier
The petrochemical, pharmaceutical, and organic industries all depend on the hydrogenation
of aromatic chemicals. Methylcyclohexan has a very high hydrogen capacity (6.22 wt%) and …

Acceptorless cross-dehydrogenative coupling for C(sp3)-H heteroarylation mediated by a heterogeneous GaN/ketone photocatalyst/photosensitizer system

H Kang, L Tan, JT Han, CY Huang, H Su… - Communications …, 2023 - nature.com
Alkanes are naturally abundant chemical building blocks that contain plentiful C (sp 3)-H
bonds. While inert, the activation of C (sp 3)-H via hydrogen atom abstraction (HAT) stages …

Gallium-based materials for electrocatalytic and photocatalytic hydrogen evolution reaction

C Liu, J Ma, Z Fu, P Zhao, M Bai, Y Gao, M Zhao… - International Journal of …, 2024 - Elsevier
Clean energy hydrogen is a promising substitute for traditional fossil fuels. Hydrogen
production via electrocatalytic and photocatalytic water splitting is attracting much attention …

Palladium nanoparticles on gallium nitride as a Mott–Schottky catalyst for efficient and durable photoactivation of unactivated alkanes

L Tan, X Kong, M Liu, H Su, H Guo, CJ Li - Chemical Science, 2023 - pubs.rsc.org
The direct functionalization of inert C–H bonds has long been a “holy grail” for the chemistry
world. In this report, the direct C (sp3)–N bond formation of unactivated alkanes is reported …

Photosynthesis of CH3OH via oxygen-atom-grafting from CO2 to CH4 enabled by AuPd/GaN

H Su, JT Han, B Miao, M Salehi, CJ Li - Nature Communications, 2024 - nature.com
The direct co-conversion of methane and carbon dioxide into valuable chemicals has been
a longstanding scientific pursuit for carbon neutrality and combating climate change. Herein …

Reduction of supported GaN and its application in methane conversion

K Trangwachirachai, AL Huang, HK Chen… - Materials Today …, 2023 - Elsevier
The reduction of supported GaN using amorphous SiO 2, silicalite-1 (S1), and HZSM-5 (HZ)
as the carriers was investigated and tested for methane conversion to acetonitrile (ACN) …

Eco-friendly CaO-based catalysts derived from waste oyster shells for the oxidative coupling of methane

JH Cho, S Kim, KT Park, CH Rhee, HW Park… - Journal of Material …, 2023 - Springer
In this study, we developed an economical and eco-friendly high-performance catalyst for
the oxidative coupling of methane from waste oyster shells, which cause environmental …

Connection of thermodynamics and kinetics in oxidation reactions catalyzed by transition metals and oxides

WT Broomhead, YHC Chin - 2024 - books.rsc.org
This chapter examines the oxidation reactions of alcohols and alkanes on transition metal or
metal oxide surfaces. The diverse sets of reactions, including oxidative dehydrogenation …

[HTML][HTML] A light-driven selective protocol for on-demand methanol and formic acid syntheses with a recyclable GaN catalyst

JT Han, H Su, L Tan, CJ Li - STAR protocols, 2023 - Elsevier
Herein, we present a protocol for the on-demand preparation of methanol and formic acid
via selective photo-oxidation of methane with H 2 O and O 2 catalyzed by GaN. The detailed …

Chemical transformations using GaN-based catalysts

JT Han, L Tan, H Su, CJ Li - 2024 - books.rsc.org
Gallium nitride (GaN), a wide bandgap III–V semiconductor, has been extensively applied in
lighting, electronics, and radiofrequency devices over the last few decades. With the distinct …