Conspectus The development of palladium-catalyzed cross-coupling methods for the
activation of C (sp2)–Br bonds facilitated access to arene-rich molecules, enabling a …

Conspectus Transition-metal catalyzed cross-coupling reactions are fundamental reactions
in organic chemistry, facilitating strategic bond formations for accessing natural products …

A useful protocol for achieving decarboxylative cross-coupling (DCC) of redox-active esters
(RAE, isolated or generated in situ) and halo (hetero) arenes is reported. This pragmatically …

The interaction between an electronically excited photocatalyst and an organic molecule
can result in the genertion of a diverse array of reactive intermediates that can be …

This review, with over 600 references, summarizes the recent applications of photoredox
catalysis for organic transformation and polymer synthesis. Photoredox catalysts are metallo …

Triplet ketone sensitizers are of central importance within the realm of photochemical
transformations. Although the radical-type character of triplet excited states of diaryl ketones …

An iridium photocatalyst and visible light facilitate a room temperature, nickel-catalyzed
coupling of (hetero) aryl bromides with activated α-heterosubstituted or benzylic C (sp3)–H …

A systematic, user‐friendly assessment tool that delivers a clear overview of the sensitivity of
reactions to key parameters is highly desirable. Herein, the development of such a method is …

Ni-catalyzed cross-couplings of aryl, benzyl, and alkyl thiols with aryl and heteroaryl iodides
were accomplished in the presence of an Ir-photoredox catalyst. Highly chemoselective C–S …

Photoredox catalysis has emerged as a powerful tool for the synthetic chemist to access
challenging targets and to generate new structural complexity. This review focuses on the …