Control, modulation, and analytical descriptions of vibrational strong coupling

BS Simpkins, AD Dunkelberger, I Vurgaftman - Chemical Reviews, 2023 - ACS Publications
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …

Light–matter interactions in hybrid material metasurfaces

J Guan, JE Park, S Deng, MJH Tan, J Hu… - Chemical …, 2022 - ACS Publications
This Review focuses on the integration of plasmonic and dielectric metasurfaces with
emissive or stimuli-responsive materials for manipulating light–matter interactions at the …

Polariton panorama

DN Basov, A Asenjo-Garcia, PJ Schuck, X Zhu… - …, 2020 - degruyter.com
In this brief review, we summarize and elaborate on some of the nomenclature of polaritonic
phenomena and systems as they appear in the literature on quantum materials and …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

Molecular orbital theory in cavity QED environments

RR Riso, TS Haugland, E Ronca, H Koch - Nature communications, 2022 - nature.com
Coupling between molecules and vacuum photon fields inside an optical cavity has proven
to be an effective way to engineer molecular properties, in particular reactivity. To ease the …

Polaritonic chemistry from first principles via embedding radiation reaction

C Schafer - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
The coherent interaction of a large collection of molecules with a common photonic mode
results in strong light-matter coupling, a feature that has proven highly beneficial for …

Collective strong coupling modifies aggregation and solvation

M Castagnola, TS Haugland, E Ronca… - The Journal of …, 2024 - ACS Publications
Intermolecular (Coulombic) interactions are pivotal for aggregation, solvation, and
crystallization. We demonstrate that the collective strong coupling of several molecules to a …

Polaritonic Chemistry Enabled by Non‐Local Metasurfaces

F Verdelli, YC Wei, K Joseph… - Angewandte Chemie …, 2024 - Wiley Online Library
Vibrational strong coupling can modify chemical reaction pathways in unconventional ways.
Thus far, Fabry‐Perot cavities formed by pairs of facing mirrors have been mostly utilized to …

Molecular vibrational polariton: Its dynamics and potentials in novel chemistry and quantum technology

B **ang, W **ong - The Journal of Chemical Physics, 2021 - pubs.aip.org
Molecular vibrational polaritons, a hybridized quasiparticle formed by the strong coupling
between molecular vibrational modes and photon cavity modes, have attracted tremendous …

Cavity catalysis: modifying linear free-energy relationship under cooperative vibrational strong coupling

J Lather, ANK Thabassum, J Singh, J George - Chemical science, 2022 - pubs.rsc.org
Here, we used an unconventional idea of cooperative vibrational strong coupling of solute
and solvent molecules to enhance the rate of an esterification reaction. Different derivatives …