Recent progress in creating complex and multiplexed surface-grafted macromolecular architectures

Z **e, T Gan, L Fang, X Zhou - Soft Matter, 2020 - pubs.rsc.org
Surface-grafted macromolecules, including polymers, DNA, peptides, etc., are versatile
modifications to tailor the interfacial functions in a wide range of fields. In this review, we aim …

A concise review on polymer brushes and its interaction with surfactants: An approach towards smart materials

MG Lokesh, AK Tiwari - Journal of Molecular Liquids, 2024 - Elsevier
Unique macromolecular structures known as polymer brushes are made of individual
polymer chains that are free at one end and attached to a solid surface at the other. Polymer …

Phase behavior of mixed polymer brushes grown from ultrathin coatings

W Wei, TY Kim, A Balamurugan, J Sun, R Chen… - ACS Macro …, 2019 - ACS Publications
Experimental validation of the predicted melt phase behavior of A/B mixed brush on planar
substrate is presented using poly (methyl methacrylate)(A)/polystyrene (B)(PMMA/PS) with …

Organocatalyzed atom transfer radical polymerization (ATRP) using triarylsulfonium hexafluorophosphate salt (THS) as a photocatalyst

M Li, S Wang, F Li, L Zhou, L Lei - Polymer Chemistry, 2020 - pubs.rsc.org
Triarylsulfonium hexafluorophosphate salt (THS), an organic and inexpensive compound,
was employed as a photocatalyst for atom transfer radical polymerization (ATRP) of …

Using Liquid Crystals to Probe the Organization of Helical Polypeptide Brushes Induced by Solvent Pretreatment

M Tsuei, H Tran, S Roh, CK Ober, NL Abbott - Macromolecules, 2021 - ACS Publications
Grafted polymer brushes form the basis of a versatile class of surfaces with properties that
can be tailored via choice of the chemical functional groups or architecture of the grafted …

Organocatalyzed Living Radical Polymerization of Itaconates and Self‐Assemblies of Rod− Coil Block Copolymers

K Hu, J Sarkar, J Zheng, YHM Lim… - Macromolecular Rapid …, 2020 - Wiley Online Library
Organocatalyzed living radical polymerizations of itaconates are studied, yielding low‐
dispersity linear and star polymers (Đ= Mw/Mn= 1.28− 1.46) up to Mn= 20 000 and monomer …

High-resolution nanopatterning of free-standing, self-supported helical polypeptide rod brushes via electron beam lithography

Y Huang, H Tran, CK Ober - ACS Macro Letters, 2021 - ACS Publications
In this study of nanopatterned helical poly (benzyl-l-glutamate)(PBLG) brushes, rod-type
brush arrays were fabricated via an integrated process of high-resolution lithography and …

Spontaneous tilting transition in liquid-crystalline polymer brushes

S Blaber, NM Abukhdeir, MW Matsen - Macromolecules, 2019 - ACS Publications
The equilibrium phase behavior of main-chain liquid-crystalline polymer brushes in good
solvent is investigated using self-consistent field theory. The calculation assumes semidilute …

Template Induced Assembly and Sequential Growth: New Mechanisms for the Growth of Bundlemer Nanorods and Brushes

MG Langenstein - 2024 - search.proquest.com
Proteins are incredibly complex materials. These sequence-defined polymers are capable of
assembling intro incredibly specific nanostructures through a complicated interplay of …

Equilibrium phase behaviour of liquid crystalline polymer brushes

S Blaber - 2019 - uwspace.uwaterloo.ca
Using self-consistent field theory of worm-like chains with Maier-Saupe interactions we study
the equilibrium phase behaviour of liquid crystalline (LC) polymer brushes. In a good solvent …