The B aeyer–V illiger Oxidation of Ketones and Aldehydes

GR Krow - Organic reactions, 2004 - Wiley Online Library
The oxidative conversion of alicyclic ketones into lactones with permonosulfuric acid was
discovered by Baeyer and Villiger in 1899, and in their honor the general process by which …

Recent developments in asymmetric reduction of ketones with biocatalysts

K Nakamura, R Yamanaka, T Matsuda… - Tetrahedron: Asymmetry, 2003 - Elsevier
Herein we review recent advances in the asymmetric reduction of ketones by biocatalysts.
Included are discussions on recent developments in methodologies to control …

Engineered cytochrome P450 for direct arylalkene-to-ketone oxidation via highly reactive carbocation intermediates

S Gergel, J Soler, A Klein, KH Schülke, B Hauer… - Nature Catalysis, 2023 - nature.com
Ketones are crucial intermediates in synthesis and frequent moieties in many products. The
direct regioselective synthesis of ketones from internal alkenes could simplify synthetic …

Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons

A Sagadevan, KC Hwang, MD Su - Nature Communications, 2017 - nature.com
Singlet O2 is a key reactive oxygen species responsible for photodynamic therapy and is
generally recognized to be chemically reactive towards C= C double bonds. Herein, we …

The Wacker reaction and related alkene oxidation reactions

JM Takacs, XT Jiang - Current Organic Chemistry, 2003 - benthamdirect.com
The objective of this review is to survey the current state of the Wacker and related alkene
oxidation reactions focusing on the reactions of higher alkenes and emphasizing the …

Chiral surfactant-type catalyst for asymmetric reduction of aliphatic ketones in water

J Li, Y Tang, Q Wang, X Li, L Cun… - Journal of the …, 2012 - ACS Publications
A novel chiral surfactant-type catalyst is developed. Micelles formed in water by association
of the catalysts themselves, and this was confirmed by TEM analyses. Asymmetric transfer …

Palladium-catalyzed heteroannulation of 1, 3-dienes by functionally substituted aryl halides

RC Larock, N Berrios-Pena… - The Journal of Organic …, 1990 - ACS Publications
Palladium-catalyzed heteroannulation of 1,3-dienes by functionally substituted aryl halides Page
1 J. Org. Chem. 3447-3450 3447 Table I. Enantioselective Wittig Reactions of Cyclohexanone …

Asymmetric Reduction of Ketones by the Acetone Powder of Geotrichum candidum

K Nakamura, T Matsuda - The Journal of Organic Chemistry, 1998 - ACS Publications
Aromatic ketones, β-keto esters, and simple aliphatic ketones were reduced with excellent
selectivity to the corresponding (S)-alcohols by using the acetone powder of Geotrichum …

Asymmetric hydrogenation of olefins with aprotic oxygen functionalities catalyzed by BINAP-Ru (II) complexes

T Ohta, T Miyake, N Seido… - The Journal of …, 1995 - ACS Publications
Cyclic,/3-unsaturated ketones, alkylidene lactones, and alkenyl ethers have been
hydrogenated in high enantiomeric excesses by use of BINAP-Ru (II) complexes (BINAP= 2 …

Thermozymes

C Vieille, DS Burdette, JG Zeikus - Biotechnology annual review, 1996 - Elsevier
Enzymes synthesized by thermophiles (organisms with optimal growth temperatures> 60° C)
and hyperthermophiles (optimal growth temperatures> 80° C) are typically thermostable …