[HTML][HTML] Recyclable inherently flame-retardant thermosets: Chemistry, properties and applications

WW Klingler, A Bifulco, C Polisi, Z Huang… - Composites Part B …, 2023 - Elsevier
Thermosets are polymeric materials that contain permanent networks and thus are difficult to
recycle. They are not reprocessable once cured and often do not degrade under mild …

[HTML][HTML] Biobased and aromatic Covalent Adaptable Networks: When architectures meet properties, within the framework of a circular bioeconomy

L Sougrati, A Duval, L Avérous - Materials Science and Engineering: R …, 2024 - Elsevier
In the current context of environmental emergency, the need for sustainable materials with
controlled end-of-life is paramount. Covalent Adaptable Networks (CANs) are a novel class …

Cardanol-based epoxy vitrimer/carbon fiber composites with integrated mechanical, self-healing, reprocessable, and welding properties and degradability

Y Hu, S Tong, Y Sha, J Yu, L Hu, Q Huang, P Jia… - Chemical Engineering …, 2023 - Elsevier
Thermosetting plastics cannot be reprocessed and recycled due to their permanent and
strong covalent cross-linking bonds, and their use could result in serious environmental …

Functional bio-based vitrimer with excellent healing and recyclability based on conjugated deflection self-toughening

P Chen, Y Ding, Y Wang, H Zhao, P Li, Y Liu… - Chemical Engineering …, 2023 - Elsevier
The three-dimensional network crosslinking structure of a vitrimer provides excellent
mechanical strength and thermal stability, which are crucial for practical applications …

A self-healable and highly flame retardant TiO2@ MXene/P, N-containing polyimine nanocomposite for dual-mode fire sensing

Y Mao, S Shi, L Lei, C Wang, D Wang, J Hu… - Chemical Engineering …, 2024 - Elsevier
Scalable early fire warning sensors that integrate passive flame-retardant strategies and
active fire alarm sensing are highly requirable in diverse areas. However, the single-mode …

Versatile levulinic acid-derived dynamic covalent thermosets enabled by in situ generated imine and multiple hydrogen bonds

Y Liu, Z Yu, G Lu, W Chen, Z Ye, Y He, Z Tang… - Chemical Engineering …, 2023 - Elsevier
Bio-based dynamic covalent thermosets have attracted extensive attention as they are
expected to break conventional thermosets' reliance on fossil resources and address the …

Upcycling waste polycarbonate to poly (carbonate imine) vitrimers with high thermal properties and unprecedented hydrolytic stability

KSK Reddy, YC Chen, RJ Jeng… - ACS Sustainable …, 2023 - ACS Publications
The global market for polycarbonate (PC) increases steadily because of its heat resistance,
toughness, and optical transparency. To achieve sustainability, the waste polycarbonate …

Fully bio-based thermosetting polyimine vitrimers with excellent adhesion, rapid self-healing, multi-recyclability and antibacterial ability

P Li, J Zhang, J Ma, CA Xu, X Liang, T Yuan… - Industrial Crops and …, 2023 - Elsevier
Traditional thermosetting materials cannot be degraded, recycled, or reprocessed once they
attain their end-of-life causing environmental pollution. Using renewable feedstocks to …

Review of reversible dynamic bonds containing intrinsically flame retardant biomass thermosets

MA Rashid, W Liu, Y Wei, Q Jiang - European Polymer Journal, 2022 - Elsevier
Thermosets are widely used in the polymer, composite, automobile, aerospace, and
electronic industries due to their excellent mechanical, thermal, light weight, and …

A critical review of sustainable vanillin-modified vitrimers: synthesis, challenge and prospects

MA Rashid, MN Hasan, MAR Dayan, MS Ibna Jamal… - Reactions, 2023 - mdpi.com
Nearly 90% of thermosets are produced from petroleum resources, they have remarkable
mechanical characteristics, are chemically durable, and dimensionally stable. However, they …