Theoretical modeling of electrochemical proton-coupled electron transfer

RE Warburton, AV Soudackov… - Chemical …, 2022 - ACS Publications
Proton-coupled electron transfer (PCET) plays an essential role in a wide range of
electrocatalytic processes. A vast array of theoretical and computational methods have been …

Biochemistry and theory of proton-coupled electron transfer

A Migliore, NF Polizzi, MJ Therien… - Chemical reviews, 2014 - ACS Publications
Through incremental change, Nature reworks and repurposes its functional machinery. In
this way, proteins that photochemically repair DNA by moving protons and electrons have a …

Proton-coupled electron transfer

MHV Huynh, TJ Meyer - Chemical reviews, 2007 - ACS Publications
At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …

Proton-coupled electron transfer

RI Cukier, DG Nocera - Annual review of physical chemistry, 1998 - annualreviews.org
▪ Abstract Proton-coupled electron transfer (PCET) is an important mechanism for charge
transfer in a wide variety of systems including biology-and materials-oriented venues. We …

Radical initiation in the class I ribonucleotide reductase: long-range proton-coupled electron transfer?

JA Stubbe, DG Nocera, CS Yee, MCY Chang - Chemical reviews, 2003 - ACS Publications
Ribonucleotide reductases (RNRs) catalyze the conversion of nucleotides to
deoxynucleotides in all organisms (eq 1). 1-3 These enzymes play an essential role in DNA …

Proton-coupled electron transfer in biology: results from synergistic studies in natural and model systems

SY Reece, DG Nocera - Annual review of biochemistry, 2009 - annualreviews.org
Proton-coupled electron transfer (PCET) underpins energy conversion in biology. PCET may
occur with the unidirectional or bidirectional transfer of a proton and electron and may …

The possible role of proton‐coupled electron transfer (PCET) in water oxidation by photosystem II

TJ Meyer, MHV Huynh, HH Thorp - … Chemie International Edition, 2007 - Wiley Online Library
All higher life forms use oxygen and respiration as their primary energy source. The oxygen
comes from water by solar‐energy conversion in photosynthetic membranes. In green …

[BUCH][B] Isotope effects in chemistry and biology

A Kohen, HH Limbach - 2005 - taylorfrancis.com
The field of isotope effects has expanded exponentially in the last decade, and researchers
are finding isotopes increasingly useful in their studies. Bringing literature on the subject up …

Going the distance: long-range conductivity in protein and peptide bioelectronic materials

NL Ing, MY El-Naggar… - The Journal of Physical …, 2018 - ACS Publications
Bioelectronic materials interface biomolecules, cells, organs, or organisms with electronic
devices, and they represent an active and growing field of materials research. Protein and …

Proton-coupled electron transfer: the mechanistic underpinning for radical transport and catalysis in biology

SY Reece, JM Hodgkiss… - … Transactions of the …, 2006 - royalsocietypublishing.org
Charge transport and catalysis in enzymes often rely on amino acid radicals as
intermediates. The generation and transport of these radicals are synonymous with proton …