A review on particle size effect in metal‐catalyzed heterogeneous reactions

H Wang, J Lu - Chinese Journal of Chemistry, 2020 - Wiley Online Library
Size of metal nanoparticles (NPs) plays decisive roles in metal‐catalyzed heterogeneous
reactions, due to the drastic variation of the geometric and electronic properties of metal NPs …

Pentagonal symmetry and disclinations in small particles

VG Gryaznov, J Heydenreich… - … of Experimental and …, 1999 - Wiley Online Library
A comprehensive review is given on experimental studies of small particles with fivefold
symmetry accompanied by an in‐depth theoretical description of their characteristics and …

Catalytic steam reforming

JR Rostrup-Nielsen - Catalysis: Science and Technology Volume 5, 1984 - Springer
I. Energy Converter. 2. Ammonia Plant.. 3. Reducing Gas Plant B. The Tubular Reformer 1.
Furnace Types 2. Tube Design... C. Reformer Models.. I. Simulation of Furnace Chamber. 2 …

Experimental studies of small particle structures

LD Marks - Reports on Progress in Physics, 1994 - iopscience.iop.org
Data on the experimental structure of small particles is reviewed, the emphasis being an
attempt to correlate experimental information with theoretical models. First, a general …

The influence of particle size on the catalytic properties of supported metals

M Che, CO Bennett - Advances in Catalysis, 1989 - Elsevier
Publisher Summary Metals constitute a wide class of catalysts, and because catalysis occurs
on the surface, there is an economic incentive, especially for precious metals, to obtain …

Selective hydrogenation of ethyne in ethene‐rich streams on palladium catalysts, Part 2: Steady‐state kinetics and effects of palladium particle size, carbon monoxide …

A Borodziński, GC Bond - Catalysis Reviews, 2008 - Taylor & Francis
Developments in the last three decades of kinetics of selective hydrogenation of ethyne in
ethene‐rich streams on palladium catalysts are reviewed. Most of the studies can be …

The effect of gold particle size on AuAu bond length and reactivity toward oxygen in supported catalysts

JT Miller, AJ Kropf, Y Zha, JR Regalbuto, L Delannoy… - Journal of …, 2006 - Elsevier
Au catalysts with different metallic particle sizes and supported on silica, alumina, titania,
zirconia, ceria, and niobia were prepared, and the reduced catalysts were characterized by …

Relation between crystallite size and dispersion on supported metal catalysts

A Borodziński, M Bonarowska - Langmuir, 1997 - ACS Publications
Universal mathematical relations between the mean relative size of metallic crystallites (d rel
(VS)) and their dispersion (FE) in supported metal catalysts have been developed. The …

Effect of gold loading and TiO2 support composition on the activity of Au/TiO2 photocatalysts for H2 production from ethanol–water mixtures

V Jovic, WT Chen, D Sun-Waterhouse, MG Blackford… - Journal of catalysis, 2013 - Elsevier
This paper systematically compares the activity of Au/TiO 2 photocatalysts (Au loadings 0–
10 wt.%) for H 2 production from ethanol–water mixtures under UV excitation. Degussa P25 …

The origins of particle size effects in heterogeneous catalysis

GC Bond - Surface Science, 1985 - Elsevier
Model calculations are presented to show how the fraction of atoms at the surface of small
metal particles increases as their size diminishes in the range 10 to 2 nm. Such particles are …