Inorganic All‐Solid‐State Sodium Batteries: Electrolyte Designing and Interface Engineering

Y Yang, S Yang, X Xue, X Zhang, Q Li, Y Yao… - Advanced …, 2024 - Wiley Online Library
Inorganic all‐solid‐state sodium batteries (IASSSBs) are emerged as promising candidates
to replace commercial lithium‐ion batteries in large‐scale energy storage systems due to …

Halide solid-state electrolytes for all-solid-state batteries: structural design, synthesis, environmental stability, interface optimization and challenges

B Tao, D Zhong, H Li, G Wang, H Chang - Chemical Science, 2023 - pubs.rsc.org
Since the huge breakthrough in 2018, research on halide solid-state electrolytes (SSEs) has
set off a new craze. In comparison with oxide and sulfide SSEs, halide SSEs have more …

Unlocking lithium ion conduction in lithium metal fluorides

L Qian, B Singh, Z Yu, N Chen, G King, Z Arthur… - Matter, 2024 - cell.com
Here, we demonstrate that quasi-crystalline lithium metal fluoride materials prepared by
mechanochemical synthesis exhibit up to 300-fold higher ionic conductivity than their …

The importance of A-site cation chemistry in superionic halide solid electrolytes

K Barker, SL McKinney, R Artal, R Jiménez… - Nature …, 2024 - nature.com
Halide solid electrolytes do not currently display ionic conductivities suitable for high-power
all-solid-state batteries. We explore the model system A2ZrCl6 (A= Li, Na, Cu, Ag) to …

NaTaCl6: Chloride as the End-Member of Sodium-Ion Conductors

K Motohashi, H Tsukasaki, A Sakuda, S Mori… - ACS Materials …, 2024 - ACS Publications
All-solid-state sodium batteries are beneficial owing to their high energy density, safety, and
abundance. Solid electrolytes are key materials in the improvement of the construction and …

Synthesis-Controlled Cation Solubility in Solid Sodium Ion Conductors Na2+xZr1–xInxCl6

T Zhao, AN Sobolev, R Schlem, B Helm… - ACS Applied Energy …, 2023 - ACS Publications
Mechanochemically synthesized sodium halide solid solutions with the general formula
Na2+ x Zr1–x M x Cl6, as a class of potential catholytes, show promising ionic transport in …

Sodium Metal Oxyhalides NaMOCl4 (M = Nb, Ta) with High Ionic Conductivities

T Zhao, B Samanta, XM de Irujo-Labalde… - ACS Materials …, 2024 - ACS Publications
Halide-based ionic conductors have attracted growing interest as solid electrolyte
candidates because of their suggested electrochemical oxidation stability and deformability …