Topological analysis of the metal-metal bond: A tutorial review

C Lepetit, P Fau, K Fajerwerg, ML Kahn… - Coordination Chemistry …, 2017 - Elsevier
This contribution explains how the topological methods of analysis of the electron density
and related functions such as the electron localization function (ELF) and the electron …

Noncovalent interactions in organometallic chemistry: from cohesion to reactivity, a new chapter

Y Cornaton, JP Djukic - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Noncovalent interactions (NCIs) have long interested a vast community of
chemists who investigated their “canonical categories” derived from descriptive …

Implementation of cooperative designs in polarized transition metal systems—significance for bond activation and catalysis

B Chatterjee, WC Chang, S Jena, C Werle - ACS Catalysis, 2020 - ACS Publications
Bond activation and catalysis are central to the development of a sustainable energy system.
Frustrated Lewis Pairs have conceptually revolutionized the activation of inert chemical …

Molecularly Controlled Catalysis–Targeting Synergies Between Local and Non‐local Environments

B Chatterjee, WC Chang, C Werlé - ChemCatChem, 2021 - Wiley Online Library
Future chemicals should preserve the efficiency of their function while reducing hazards and
waste. In this context, catalysis–a fundamental pillar of Green Chemistry–is still the most …

Interpretation of Tolman electronic parameters in the light of natural orbitals for chemical valence

GA Ardizzoia, S Brenna - Physical Chemistry Chemical Physics, 2017 - pubs.rsc.org
Understanding the nature and the strength of metal–ligand interactions in d-and f-block
metal complexes has always been a central issue for both synthetic and theoretical …

A Quantitative Description of the σ‐Donor and π‐Acceptor Properties of Substituted Phenanthrolines

GA Ardizzoia, M Bea, S Brenna… - European Journal of …, 2016 - Wiley Online Library
The bond between molybdenum and substituted 1, 10‐phenanthroline ligands in a series of
[Mo (CO) 4 (phen*)] complexes has been studied by combining experimental data (νCO) …

trans–cis C–Pd–C rearrangement in hemichelates

C Werlé, S Dohm, C Bailly, L Karmazin, L Ricard… - Dalton …, 2017 - pubs.rsc.org
Kinetically unstable heteroleptic trans-bispalladacycles were isolated by using
hemichelation. Three structures of trans isomers and five of cis isomers were characterized …

Effect of Enhanced Electron Withdrawal on the Cohesion of Cr‐Pd Hemichelates

C Werlé, L Karmazin, C Bailly… - European Journal of …, 2019 - Wiley Online Library
Two new trimetallic Cr‐Pd hemichelates containing a fluorenyl moiety and two trans arene‐
bound Cr (CO) 3 moieties were synthesized and fully characterized. Their molecular …

μ-Carbonyl-bis (carbonyl {η5-[tricarbonyl (η6-2-methylindenyl) chromium (0)] rhodium (III)})(Rh—Rh)

C Werlé, C Bailly, L Karmazin, JP Djukic - IUCrData, 2019 - journals.iucr.org
The structure of the title complex,[Cr2Rh2 (C10H9) 2 (CO) 9], was solved by single-crystal X-
ray diffraction analysis in the P21/c space group. The crystal shows two units of the …