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Topological analysis of the metal-metal bond: A tutorial review
C Lepetit, P Fau, K Fajerwerg, ML Kahn… - Coordination Chemistry …, 2017 - Elsevier
This contribution explains how the topological methods of analysis of the electron density
and related functions such as the electron localization function (ELF) and the electron …
and related functions such as the electron localization function (ELF) and the electron …
Noncovalent interactions in organometallic chemistry: from cohesion to reactivity, a new chapter
Y Cornaton, JP Djukic - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Noncovalent interactions (NCIs) have long interested a vast community of
chemists who investigated their “canonical categories” derived from descriptive …
chemists who investigated their “canonical categories” derived from descriptive …
Implementation of cooperative designs in polarized transition metal systems—significance for bond activation and catalysis
Bond activation and catalysis are central to the development of a sustainable energy system.
Frustrated Lewis Pairs have conceptually revolutionized the activation of inert chemical …
Frustrated Lewis Pairs have conceptually revolutionized the activation of inert chemical …
Molecularly Controlled Catalysis–Targeting Synergies Between Local and Non‐local Environments
Future chemicals should preserve the efficiency of their function while reducing hazards and
waste. In this context, catalysis–a fundamental pillar of Green Chemistry–is still the most …
waste. In this context, catalysis–a fundamental pillar of Green Chemistry–is still the most …
Interpretation of Tolman electronic parameters in the light of natural orbitals for chemical valence
Understanding the nature and the strength of metal–ligand interactions in d-and f-block
metal complexes has always been a central issue for both synthetic and theoretical …
metal complexes has always been a central issue for both synthetic and theoretical …
A Quantitative Description of the σ‐Donor and π‐Acceptor Properties of Substituted Phenanthrolines
The bond between molybdenum and substituted 1, 10‐phenanthroline ligands in a series of
[Mo (CO) 4 (phen*)] complexes has been studied by combining experimental data (νCO) …
[Mo (CO) 4 (phen*)] complexes has been studied by combining experimental data (νCO) …
trans–cis C–Pd–C rearrangement in hemichelates
C Werlé, S Dohm, C Bailly, L Karmazin, L Ricard… - Dalton …, 2017 - pubs.rsc.org
Kinetically unstable heteroleptic trans-bispalladacycles were isolated by using
hemichelation. Three structures of trans isomers and five of cis isomers were characterized …
hemichelation. Three structures of trans isomers and five of cis isomers were characterized …
Effect of Enhanced Electron Withdrawal on the Cohesion of Cr‐Pd Hemichelates
C Werlé, L Karmazin, C Bailly… - European Journal of …, 2019 - Wiley Online Library
Two new trimetallic Cr‐Pd hemichelates containing a fluorenyl moiety and two trans arene‐
bound Cr (CO) 3 moieties were synthesized and fully characterized. Their molecular …
bound Cr (CO) 3 moieties were synthesized and fully characterized. Their molecular …
μ-Carbonyl-bis (carbonyl {η5-[tricarbonyl (η6-2-methylindenyl) chromium (0)] rhodium (III)})(Rh—Rh)
C Werlé, C Bailly, L Karmazin, JP Djukic - IUCrData, 2019 - journals.iucr.org
The structure of the title complex,[Cr2Rh2 (C10H9) 2 (CO) 9], was solved by single-crystal X-
ray diffraction analysis in the P21/c space group. The crystal shows two units of the …
ray diffraction analysis in the P21/c space group. The crystal shows two units of the …