Are ionic liquids eco-friendly?

SS de Jesus, R Maciel Filho - Renewable and Sustainable Energy …, 2022 - Elsevier
Ionic liquids are molten salts that have excellent chemical and thermal stability. Because
they have qualities inherent to some precepts of green chemistry, they are identified as a …

Homogeneous functionalization of methane

NJ Gunsalus, A Koppaka, SH Park, SM Bischof… - Chemical …, 2017 - ACS Publications
One of the remaining “grand challenges” in chemistry is the development of a next
generation, less expensive, cleaner process that can allow the vast reserves of methane …

Trifluoromethyltrimethylsilane: nucleophilic trifluoromethylation and beyond

X Liu, C Xu, M Wang, Q Liu - Chemical reviews, 2015 - ACS Publications
Method B 692 3.7. Selective Trifluoromethylation of Multi-Functional Substrates 693 3.8.
Enantioselective Trifluoromethylation 695 3.8. 1. Aldehydes and Ketones: With Cinchona …

Brønsted acidity in metal–organic frameworks

J Jiang, OM Yaghi - Chemical reviews, 2015 - ACS Publications
The past 20 years have witnessed rapid development of reticular chemistry, 1, 2 which is
concerned with linking molecular building units with strong chemical bonds to form …

Lewis superacids: classifications, candidates, and applications

L Greb - Chemistry–A European Journal, 2018 - Wiley Online Library
Lewis acids play a major role in all areas of chemistry. For a long time, toxic, corrosive and
oxidizing SbF5 was considered as the strongest Lewis acid known. Lately, species …

Superacidity in sulfated metal–organic framework-808

J Jiang, F Gándara, YB Zhang, K Na… - Journal of the …, 2014 - ACS Publications
Superacids, defined as acids with a Hammett acidity function H 0≤− 12, are useful
materials, but a need exists for new, designable solid state systems. Here, we report …

Advances in methane conversion processes

B Wang, S Albarracín-Suazo, Y Pagán-Torres… - Catalysis Today, 2017 - Elsevier
In this short review, we highlight the recent advances in methane conversion processes at
high and low temperatures. Methane conversion processes are of great importance in …

Calix[4]pyrrolato-germane-(thf)2: Unlocking the Anti-van't Hoff–Le Bel Reactivity of Germanium(IV) by Ligand Dissociation

R Yadav, P Janßen, M Schorpp… - Journal of the American …, 2023 - ACS Publications
Anti-van't Hoff–Le Bel configured p-block element species possess intrinsically high
reactivity and are thus challenging to isolate. Consequently, numerous elements in this …

Binding, Sensing, And Transporting Anions with Pnictogen Bonds: The Case of Organoantimony Lewis Acids

BL Murphy, FP Gabbaï - Journal of the American Chemical …, 2023 - ACS Publications
Motivated by the discovery of main group Lewis acids that could compete or possibly
outperform the ubiquitous organoboranes, several groups, including ours, have engaged in …

Nontraditional catalyst supports in surface organometallic chemistry

RJ Witzke, A Chapovetsky, MP Conley… - ACS …, 2020 - ACS Publications
The field of Surface Organometallic Chemistry (SOMC) aims to blend the positive attributes
of homogeneous and heterogeneous catalysis. Significant insight into heterogeneous …