Heterocycles are an extraordinarily important class of compounds, making up more than half
of all known organic compounds. Heterocycles are present in a wide variety of drugs, most …

Catalytic asymmetric carbon–carbon bond‐forming reactions provide one of the most
efficient ways to synthesize optically active compounds, and, accordingly, many chiral …

The development of robust and reactive chiral catalysts is a fundamental aim in asymmetric
catalysis, and crucial for providing efficient methods for synthesizing chiral molecules. Chiral …

Dirhodiums, which feature lantern-or paddlewheel-like structures, have emerged as a class
of useful catalysts in organic synthesis. Among the transformations catalyzed by dirhodiums …

The design and use of chiral dirhodium (II) paddlewheel complexes as catalysts for
asymmetric metal carbenoid and metal nitrenoid reactions, and as Lewis acids have …

Dirhodium compounds are emerging as highly efficient catalysts for diverse reactions, and
those with carboxamidate ligands have the broadest applications. The unique features of …

This review is focused on the enantioselective synthesis of 3, 4-dihydropyran derivatives,
whose importance as chiral building blocks in the synthesis of bioactive molecules and …

Since its discovery in 1928 by Diels and Alder, 1 the Diels–Alder reaction has become one
of the cornerstone reactions in organic chemistry for the construction of six-membered rings …

Dirhodium (II) tetrakis [N-tetrachlorophthaloyl-(S)-tert-leucinate], characterized by
substitution of chlorine atoms for four hydrogen atoms on the phthalimido group in the parent …

The use of a rhodium (II) carboxylate catalyst enables the mild and stereoselective formation
of carbazoles from biaryl azides. Intramolecular competition experiments of triaryl azides …