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Elucidating the speciation of extracted lanthanides by diglycolamides
Many studies over the past few decades have been devoted to addressing the application of
diglycolamides (DGAs) for hydrometallurgical-based, f-element separations. Work to date …
diglycolamides (DGAs) for hydrometallurgical-based, f-element separations. Work to date …
Enhanced binding of SARS-CoV-2 spike protein to receptor by distal polybasic cleavage sites
The receptor-binding domain (RBD) of the SARS-CoV-2 spike protein plays a crucial role in
binding the human cell receptor ACE2 that is required for viral entry. Many studies have …
binding the human cell receptor ACE2 that is required for viral entry. Many studies have …
Complexation chemistry in liquid–liquid extraction of rhenium
RR Srivastava, J Lee, M Kim - Journal of Chemical Technology …, 2015 - Wiley Online Library
This review addresses the dearth of knowledge about the interaction of rhenium species
with organic solvents during the liquid–liquid extraction of rhenium. To describe such …
with organic solvents during the liquid–liquid extraction of rhenium. To describe such …
Molecular forces in liquid–liquid extraction
The phase transfer of ions is driven by gradients of chemical potentials rather than
concentrations alone (ie, by both the molecular forces and entropy). Extraction is a …
concentrations alone (ie, by both the molecular forces and entropy). Extraction is a …
Synergistic solvent extraction is driven by entropy
In solvent extraction, the self-assembly of amphiphilic molecules into an organized structure
is the phenomenon responsible for the transfer of the metal ion from the aqueous phase to …
is the phenomenon responsible for the transfer of the metal ion from the aqueous phase to …
[HTML][HTML] Solvent extraction in non-ideal eutectic solvents–Application towards lanthanide separation
Hydrophobic eutectic solvents (HES) emerged as promising substitutes to the conventional
organic phase used in the solvent extraction (SX) of metal ions due to the avoidance of …
organic phase used in the solvent extraction (SX) of metal ions due to the avoidance of …
Complexation‐Induced Supramolecular Assembly Drives Metal‐Ion Extraction
RJ Ellis, Y Meridiano, J Muller, L Berthon… - … A European Journal, 2014 - Wiley Online Library
Combining experiment with theory reveals the role of self‐assembly and complexation in
metal‐ion transfer through the water–oil interface. The coordinating metal salt Eu (NO3) 3 …
metal‐ion transfer through the water–oil interface. The coordinating metal salt Eu (NO3) 3 …
A telesco** view of solute architectures in a complex fluid system
R Motokawa, T Kobayashi, H Endo, J Mu… - ACS central …, 2018 - ACS Publications
Short-and long-range correlations between solutes in solvents can influence the
macroscopic chemistry and physical properties of solutions in ways that are not fully …
macroscopic chemistry and physical properties of solutions in ways that are not fully …
Ion transport mechanisms in liquid–liquid interface
Interfacial liquid–liquid ion transport is of crucial importance to biotechnology and industrial
separation processes including nuclear elements and rare earths. A water-in-oil …
separation processes including nuclear elements and rare earths. A water-in-oil …
Critical fluctuations in liquid–liquid extraction organic phases controlled by extractant and diluent molecular structure
Extractant aggregation in liquid–liquid extraction organic phases impacts extraction
energetics and is related to the deleterious efficiency-limiting liquid–liquid phase transition …
energetics and is related to the deleterious efficiency-limiting liquid–liquid phase transition …