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Selective carbon–carbon bond cleavage of cyclopropanols
TR McDonald, LR Mills, MS West… - Chemical …, 2020 - ACS Publications
The carbon–carbon (C–C) bond cleavage of cyclopropanols is a wide area of research with
much current activity. This review highlights new developments in this area over the past two …
much current activity. This review highlights new developments in this area over the past two …
Creating stereocenters within acyclic systems by C–C bond cleavage of cyclopropanes
Recent developments in the stereoselective synthesis of polysubstituted cyclopropanes
nowadays allow chemists to easily access these strained rings with high diastereo-and …
nowadays allow chemists to easily access these strained rings with high diastereo-and …
Cobalt-catalyzed diastereo-and enantioselective carbon–carbon bond forming reactions of cyclobutenes
Z Liang, L Wang, Y Wang, L Wang… - Journal of the …, 2023 - ACS Publications
Catalytic enantioselective functionalization of cyclobutenes constitutes a general and
modular strategy for construction of enantioenriched complex cyclobutanes bearing multiple …
modular strategy for construction of enantioenriched complex cyclobutanes bearing multiple …
Intramolecular photochemical [2+ 1]-cycloadditions of nucleophilic siloxy carbenes
Visible light induced singlet nucleophilic carbenes undergo rapid [2+ 1]-cycloaddition with
tethered olefins to afford unique bicyclo [3.1. 0] hexane and bicyclo [4.1. 0] heptane …
tethered olefins to afford unique bicyclo [3.1. 0] hexane and bicyclo [4.1. 0] heptane …
Development and applications of water-compatible reactions: a journey to be continued
MZ Lu, TP Loh - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The pursuit of novel and eco-friendly methods in organic synthesis is gaining
prominence, with a strong emphasis on green transformations using renewable and …
prominence, with a strong emphasis on green transformations using renewable and …
On the Origin of Rh-Catalyzed Selective Ring-Opening Amidation of Substituted Cyclopropanols to Access β2-Amino Ketones
β2-Amino carbonyls, an α-substituted β-amino scaffold, hold a prominent place in the
development of new pharmaceuticals and peptidomimetics. Herein, we report a highly …
development of new pharmaceuticals and peptidomimetics. Herein, we report a highly …
Organophotocatalytic carbo-heterofunctionalization of unactivated olefins with pendant nucleophiles
We report the difunctionalization of unactivated, terminal olefins through intermolecular
addition of α-bromoketones,-esters, and-nitriles followed by formation of 4-to 6-membered …
addition of α-bromoketones,-esters, and-nitriles followed by formation of 4-to 6-membered …
A Homo‐Mannich Reaction Strategy Enables Collective Access to Ibophyllidine, Aspidosperma, Kopsia, and Melodinus Alkaloids
D Jiang, P Tang, H **ong, S Lei… - Angewandte Chemie …, 2023 - Wiley Online Library
We report here a homo‐Mannich reaction of cyclopropanol with an iminium ion, generated
by an asymmetric allylic dearomatization of indole, to construct a tricyclic hydrocarbazole …
by an asymmetric allylic dearomatization of indole, to construct a tricyclic hydrocarbazole …
Iron-catalyzed ring-opening reactions of cyclopropanols with alkenes and TBHP: synthesis of 5-oxo peroxides
C Lou, X Wang, L Lv, Z Li - Organic Letters, 2021 - ACS Publications
The ring opening of cyclopropanols is rarely used in multicomponent reactions. Herein we
report the three-component reaction of cyclopropanols with alkenes and tert-butyl …
report the three-component reaction of cyclopropanols with alkenes and tert-butyl …
Enantioselective conjugate addition of catalytically generated zinc homoenolate
Y Sekiguchi, N Yoshikai - Journal of the American Chemical …, 2021 - ACS Publications
We report herein an enantioselective conjugate addition reaction of a zinc homoenolate,
catalytically generated via ring opening of a cyclopropanol, to an α, β-unsaturated ketone …
catalytically generated via ring opening of a cyclopropanol, to an α, β-unsaturated ketone …