Secondary batteries are a core technology for clean energy storage and conversion
systems, to reduce environmental pollution and alleviate the energy crisis. Oxide cathodes …

Current high-energy-density Li-ion batteries use stoichiometric Li 3d transition metal oxides
as positive electrodes, which are conventionally described purely by transition-metal redox …

In layered Li‐rich materials, over stoichiometric Li forms an ordered occupation of LiTM6 in
transition metal (TM) layer, showing a honeycomb superstructure along [001] direction. At …

High‐voltage cathodes (HVCs) have emerged as a paramount role for the next‐generation
high‐energy‐density lithium‐ion batteries (LIBs). However, the pursuit of HVCs comes with …

A comprehensive understanding of the relationship between the structure
(electron/bulk/surface structures) and redox chemistry in the cathodes was discussed in this …

The delamination cracking from planar gliding along the (003) facets and anisotropic lattice
strain perpendicular to the (003) facets inevitable lead to degradation of Ni‐rich single …

Lithium-rich layered oxides involving both transition metal and oxygen redox have received
widespread attention due to their high energy density. However, the participation of oxygen …

Electrochemomechanical degradation is one of the most common causes of capacity
deterioration in high-energy-density cathodes, particularly intercalation-based layered …

Solid-state Li-ion batteries, based on Ni-rich oxide cathodes and Li-metal anodes, can
theoretically reach a high specific energy of 393 Wh kg− 1 and hold promise for …

The further practical applications of Li-rich layered oxides are impeded by voltage decay
and redox asymmetry, which are closely related to the structural degradation involving …