Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Synthesis and stability of tagged UiO-66 Zr-MOFs

M Kandiah, MH Nilsen, S Usseglio… - Chemistry of …, 2010 - ACS Publications
The development in the field MOF materials is moving from the discovery of new structures
toward applications of the most promising materials. In most cases, specialized applications …

Screening of metal− organic frameworks for carbon dioxide capture from flue gas using a combined experimental and modeling approach

AO Yazaydın, RQ Snurr, TH Park, K Koh… - Journal of the …, 2009 - ACS Publications
A diverse collection of 14 metal− organic frameworks (MOFs) was screened for CO2 capture
from flue gas using a combined experimental and modeling approach. Adsorption …

Probing zeolites by vibrational spectroscopies

S Bordiga, C Lamberti, F Bonino, A Travert… - Chemical Society …, 2015 - pubs.rsc.org
This review addresses the most relevant aspects of vibrational spectroscopies (IR, Raman
and INS) applied to zeolites and zeotype materials. Surface Brønsted and Lewis acidity and …

Amino-based metal-organic frameworks as stable, highly active basic catalysts

J Gascon, U Aktay, MD Hernandez-Alonso… - Journal of …, 2009 - Elsevier
Metal-organic frameworks (MOFs) with non-coordinated amino groups, ie IRMOF-3 and
amino-functionalized MIL-53, are stable solid basic catalysts in the Knoevenagel …

CO2 adsorption in Y and X zeolites modified by alkali metal cation exchange

KS Walton, MB Abney, MD LeVan - Microporous and mesoporous …, 2006 - Elsevier
Ion exchange was performed on NaY and NaX zeolites with alkali metal cations Li+, K+,
Rb+, and Cs+ and studied by adsorption of CO2. This is the first study to examine adsorption …

One-step multiple-site integration strategy for CO2 capture and conversion into cyclic carbonates under atmospheric and cocatalyst/metal/solvent-free conditions

Q Yi, T Liu, X Wang, Y Shan, X Li, M Ding, L Shi… - Applied Catalysis B …, 2021 - Elsevier
The capture of CO 2 and subsequent conversion into high value-added chemicals under
atmospheric conditions is an on-going challenge. This work reports a facile multiple-site …

Computational and Experimental Studies on the Adsorption of CO, N2, and CO2 on Mg-MOF-74

L Valenzano, B Civalleri, S Chavan… - The Journal of …, 2010 - ACS Publications
Adsorption of carbon monoxide, dinitrogen, and carbon dioxide on the porous metal−
organic framework Mg-MOF-74 was investigated by means of a combined methodology …

Adsorption properties of HKUST-1 toward hydrogen and other small molecules monitored by IR

S Bordiga, L Regli, F Bonino, E Groppo… - Physical Chemistry …, 2007 - pubs.rsc.org
Among microporous systems metal organic frameworks are considered promising materials
for molecular adsorption. In this contribution infrared spectroscopy is successfully applied to …