Coordination-directed self-assembly of functional polynuclear lanthanide supramolecular architectures

XZ Li, CB Tian, QF Sun - Chemical Reviews, 2022 - ACS Publications
Lanthanide supramolecular chemistry is a fast growing and intriguing research field due to
the unique photophysical, magnetic, and coordination properties of lanthanide ions (LnIII) …

Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Dipolar Coupling as a Mechanism for Fine Control of Magnetic States in ErCOT-Alkyl Molecular Magnets

MG Bernbeck, AP Orlova, JD Hilgar… - Journal of the …, 2024 - ACS Publications
The design of molecular magnets has progressed greatly by taking advantage of the ability
to impart successive perturbations and control vibronic transitions in 4f n systems through …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

Exploiting single-ion anisotropy in the design of f-element single-molecule magnets

JD Rinehart, JR Long - Chemical Science, 2011 - pubs.rsc.org
Scientists have long employed lanthanide elements in the design of materials with
extraordinary magnetic properties, including the strongest magnets known, SmCo5 and …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Magnetic polyoxometalates: from molecular magnetism to molecular spintronics and quantum computing

JM Clemente-Juan, E Coronado… - Chemical Society …, 2012 - pubs.rsc.org
Magnetic polyoxometalates: from molecular magnetism to molecular spintronics and
quantum computing - Chemical Society Reviews (RSC Publishing) DOI:10.1039/C2CS35205B …

AN23– Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K

JD Rinehart, M Fang, WJ Evans… - Journal of the American …, 2011 - ACS Publications
The synthesis and magnetic properties of three new N23–radical-bridged dilanthanide
complexes,{[(Me3Si) 2N] 2 (THF) Ln} 2 (μ-η2: η2-N2)−(Ln= Tb, Ho, Er), are reported. All …

Strong exchange and magnetic blocking in N23−-radical-bridged lanthanide complexes

JD Rinehart, M Fang, WJ Evans, JR Long - Nature Chemistry, 2011 - nature.com
Single-molecule magnets approach the ultimate size limit for spin-based devices. These
complexes can retain spin information over long periods of time at low temperature …