Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Manipulating spin transition to achieve switchable multifunctions

YS Meng, T Liu - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus The spin transition of metal ions involves interconversion between electron
configurations exhibiting considerably different functions and plays a substantial role in the …

A Two‐Dimensional Iron (II) Coordination Polymer with Synergetic Spin‐Crossover and Luminescent Properties

JY Ge, Z Chen, L Zhang, X Liang, J Su… - Angewandte …, 2019 - Wiley Online Library
Abstract A composite material,{[Fe (L)(TPPE) 0.5]⋅ 3 CH3OH} n, has been constructed by
integrating the spin‐crossover (SCO) subunit FeII {diethyl (E, E)‐2, 2′‐[1, 2‐phenyl‐bis …

Shedding light on bifunctional luminescent spin crossover materials

MK Javed, A Sulaiman, M Yamashita, ZY Li - Coordination Chemistry …, 2022 - Elsevier
The spin crossover (SCO) phenomenon has witnessed remarkable progress in applications
since it was first discovered almost a century ago. Specifically, materials that exhibit SCO …

Rhodamine 6G-labeled pyridyl aroylhydrazone Fe (II) complex exhibiting synergetic spin crossover and fluorescence

J Yuan, SQ Wu, MJ Liu, O Sato… - Journal of the American …, 2018 - ACS Publications
Here, we use a pyridinecarbaldehyde rhodamine 6G hydrazone ligand (L) to synthesize an
Fe (II) complex 1 for the search of new fluorescent-spin crossover (SCO) materials. Single …

Bistable molecular materials with dynamic structures

ZS Yao, Z Tang, J Tao - Chemical communications, 2020 - pubs.rsc.org
The development of molecular materials whose physical properties can be switched
between different states has attracted significant attention for their potential application in …

Unusual metal centres/coordination spheres in spin crossover compounds

J Olguín - Coordination Chemistry Reviews, 2020 - Elsevier
The most widely studied spin crossover (SCO) systems are those involving hexacoordinate
iron (II) complexes immerse in the “magic” N 6 coordination sphere. In this review the …

Interplay between spin-crossover and luminescence in a multifunctional single crystal iron (II) complex: Towards a new generation of molecular sensors

B Benaicha, K Van Do, A Yangui, N Pittala… - Chemical …, 2019 - pubs.rsc.org
We present a new example of a mononuclear iron (II) complex exhibiting a correlated spin-
crossover (SCO) transition and strong fluorescence, whose coordination sphere is saturated …

Synergistic strategies for the synthesis of Fe (II)-based bifunctional fluorescent spin-crossover materials

K Sun, JP Xue, ZS Yao, J Tao - Dalton Transactions, 2022 - pubs.rsc.org
Spin-crossover (SCO) materials have been extensively investigated in the past few decades
with promising applications in a wide range of fields including displays, sensors, and …

Manipulating Fluorescence by Photo-switched Spin-state Conversions in an Iron (II)-based SCO-MOF

FF Yan, WJ Jiang, NT Yao, PD Mao, L Zhao… - Chemical …, 2023 - pubs.rsc.org
Manipulating fluorescence by photo-switched spin-state conversions is an attractive
prospect for applications in smart magneto-optical materials and devices. The challenge is …