Cage compounds offer unique binding pockets similar to enzyme-binding sites, which can
be customized in terms of size, shape, and functional groups to point toward the cavity and …

The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …

Microporous framework membranes such as metal–organic framework (MOF) membranes
and covalent organic framework (COF) membranes are constructed by the controlled growth …

Porous organic molecular materials are a subclass of porous solids that are defined by their
modular, molecular structures, and the absence of extended covalent or coordination …

Porous organic materials are an emerging class of functional nanostructures with
unprecedented properties. Dynamic covalent assembly of small organic building blocks …

Porosity is a rare property for molecular materials but, surprisingly, porous solids built from
discrete organic cage molecules have emerged as a versatile functional-materials platform …

Defect engineering in metal–organic frameworks (MOFs) is an exciting concept for tailoring
material properties, which opens up novel opportunities not only in sorption and catalysis …

Conspectus The interest in shape-persistent organic cages is nearly as old as the interest in
supramolecular chemistry. In the beginning, organic cages have often been synthesized in a …

The creation of metal nanoclusters with dimensions ranging from subnanometre to~ 2 nm for
heterogeneous catalysis has received substantial attention. However, synthesizing these …

Electroreduction of CO2 into valuable fuels and feedstocks offers a promising way for CO2
utilization. However, the commercialization is limited by the low productivity. Here, we report …