Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Molecular catalysts for CO2 Electroreduction: Progress and prospects with pincer type complexes

HA Younus, N Ahmad, W Ni, X Wang, M Al-Abri… - Coordination Chemistry …, 2023 - Elsevier
Transforming wastes or hazardous materials into value-added chemical products is of great
concern from economic, environmental, and sustainable prospects. Various approaches …

A Mn-N3 single-atom catalyst embedded in graphitic carbon nitride for efficient CO2 electroreduction

J Feng, H Gao, L Zheng, Z Chen, S Zeng… - Nature …, 2020 - nature.com
Develo** effective catalysts based on earth abundant elements is critical for CO2
electroreduction. However, simultaneously achieving a high Faradaic efficiency (FE) and …

[HTML][HTML] Non-noble metal single atom-based catalysts for electrochemical reduction of CO2: Synthesis approaches and performance evaluation

Y Sun, X Liu, M Zhu, Z Zhang, Z Chen, S Wang, Z Ji… - DeCarbon, 2023 - Elsevier
Limiting global carbon dioxide (CO 2) emission is imperative to alleviate global warming and
meet the growing energy demand. Electrocatalytic CO 2 reduction is a promising approach …

Rhenium chemistry–then and now

JR Dilworth - Coordination Chemistry Reviews, 2021 - Elsevier
The first section provides a background to the whole review. The second presents a
historical perspective of fundamental developments in rhenium chemistry from its discovery …

Redox-Active Ligands in Electroassisted Catalytic H+ and CO2 Reductions: Benefits and Risks

N Queyriaux - ACS Catalysis, 2021 - ACS Publications
In the past decade, the use of redox-active ligands has emerged as a promising strategy to
improve catalyst selectivity, efficiency, and stability in electroassisted H+ and CO2 …

Pincer complexes in photo-and electro-catalytic hydrogen evolution (HER) and carbon dioxide reduction reactions (CO2RR)

MAW Lawrence, C Thompson, SC Lorraine - Inorganica Chimica Acta, 2024 - Elsevier
Pincer complexes have aided in the understanding of a number of processes mediated by
transition metal compounds. In homogenous catalytic transformations, pincers as ligands …

N‐Heterocyclic and Mesoionic Carbenes of Manganese and Rhenium in Catalysis

S Friães, S Realista, H Mourão… - European Journal of …, 2022 - Wiley Online Library
The use of N‐heterocyclic carbenes (NHCs) in manganese and rhenium catalysis is
underdeveloped in comparison to other transition metals. Herein, we cover the recent and …

“Anion-Switchable” Pincer-Mn(I) Catalyst for the Reductive N-Methylation of Amines with Formic Acid and CO2

S Martínez-Vivas, S Gonell, M Poyatos, E Peris - ACS Catalysis, 2024 - ACS Publications
We report a manganese (I) complex of formula [Mn (NDI-CNC)(CO) 3](BArF4), in which NDI-
CNC refers to a pincer pyridine-bis-imidazolylidene ligand functionalized with a …

Manganese-N-heterocyclic carbene (NHC) complexes–An overview

SMPV Broeck, CSJ Cazin - Polyhedron, 2021 - Elsevier
N-heterocyclic carbenes (NHCs) have been extensively used as ligands in organometallic
complexes of the Transition Metals. This review focuses on manganese complexes bearing …