Direct laser cooling of polyatomic molecules

BL Augenbraun, L Anderegg, C Hallas… - Advances in Atomic …, 2023 - Elsevier
Over the past decade, tremendous progress has been made to extend the tools of laser
cooling and trap** to molecules. Those same tools have recently been applied to …

Magneto-optical trap** and sub-Doppler cooling of a polyatomic molecule

NB Vilas, C Hallas, L Anderegg, P Robichaud… - Nature, 2022 - nature.com
Laser cooling and trap**,, and magneto-optical trap** methods in particular, have
enabled groundbreaking advances in science, including Bose–Einstein condensation …

An optical tweezer array of ultracold polyatomic molecules

NB Vilas, P Robichaud, C Hallas, GK Li, L Anderegg… - Nature, 2024 - nature.com
Polyatomic molecules have rich structural features that make them uniquely suited to
applications in quantum information science,–, quantum simulation,–, ultracold chemistry …

Optical Trap** of a Polyatomic Molecule in an -Type Parity Doublet State

C Hallas, NB Vilas, L Anderegg, P Robichaud… - Physical Review Letters, 2023 - APS
We report optical trap** of a polyatomic molecule, calcium monohydroxide (CaOH). CaOH
molecules from a magneto-optical trap are sub-Doppler laser cooled to 20 (3) μ K in free …

Functionalizing aromatic compounds with optical cycling centres

GZ Zhu, D Mitra, BL Augenbraun, CE Dickerson… - Nature …, 2022 - nature.com
Molecular design principles provide guidelines for augmenting a molecule with a smaller
group of atoms to realize a desired property or function. We demonstrate that these concepts …

Absolute frequency metrology of buffer-gas-cooled molecular spectra at 1 kHz accuracy level

R Aiello, V Di Sarno, MG Delli Santi, M De Rosa… - Nature …, 2022 - nature.com
By reducing both the internal and translational temperature of any species down to a few
kelvins, the buffer-gas-cooling (BGC) technique has the potential to dramatically improve the …

Characterizing the fundamental bending vibration of a linear polyatomic molecule for symmetry violation searches

A Jadbabaie, Y Takahashi, NH Pilgram… - New Journal of …, 2023 - iopscience.iop.org
Polyatomic molecules have been identified as sensitive probes of charge-parity violating
and parity violating physics beyond the Standard Model (BSM). For example, many linear …

Intensity-borrowing mechanisms pertinent to laser cooling of linear polyatomic molecules

C Zhang, NR Hutzler, L Cheng - Journal of Chemical Theory and …, 2023 - ACS Publications
A study of the intensity-borrowing mechanisms important to optical cycling transitions in
laser-coolable polyatomic molecules arising from non-adiabatic coupling, contributions …

Zeeman-Sisyphus deceleration of molecular beams

BL Augenbraun, A Frenett, H Sawaoka, C Hallas… - Physical Review Letters, 2021 - APS
We present a robust, continuous molecular decelerator that employs high magnetic fields
and few optical pum** steps. CaOH molecules are slowed, accumulating at low velocities …

Optical cycling in polyatomic molecules with complex hyperfine structure

Y Zeng, A Jadbabaie, AN Patel, P Yu, TC Steimle… - Physical Review A, 2023 - APS
We have developed and demonstrated a scheme to achieve rotationally closed photon
cycling in polyatomic molecules with complex hyperfine structure and sensitivity to hadronic …