This review summarizes the electronic coupling studies in mixed-valence or donor–acceptor-
type complexes containing one or two cyclometalated ruthenium redox sites. Basic electron …

Cyanido-bridged multimetallic complexes have been extensively studied for their potential
applications in molecular electronics and spintronics. The design of these complexes …

The Class II–III mixed-valence species have attracted great attention because of the
borderline behavior in the Class II to Class III transition. To further investigate those species …

Chromophore–catalyst assemblies are interesting benchmark molecules for photocatalysis.
We have prepared two examples of these assemblies and characterized their behaviour as …

Upon MLCT photoexcitation,{(tpy) Ru} becomes the electron acceptor in the mixed valence
{(tpy˙−) RuIII− δ-NC-MII+ δ} moiety, reversing its role as the electron donor in the ground …

In this work, we report the evolution of the properties of the inter-valence charge transfer
(IVCT) transition in a family of cyanide-bridged ruthenium polypyridines of general formula …

Bimetallic trans-[RuII (tpm)(bpy)(μNC) RuII (L) 4 (CN)] 2+, where bpy is 2, 2′-bipyridine, tpm
is tris (1-pyrazolyl) methane and L= 4-methoxypyridine (MeOpy) or pyridine (py), was …

The exploitation of excited state chemistry for solar energy conversion or photocatalysis has
been continuously increasing, and the needs of a transition to a sustainable human …

We investigated how substitution of the ligand around the lower valent metal ion influences
the electron transfer properties from the lower valent metal ion to the higher valent metal ion …

Photoexcitation of [Ru (tpy)(bpy)(μ-CN) Ru (py) 4Cl] 2+([RuRu] 2+) at 387 nm results in the
population of two 3MLCT excited states of different symmetry that coexist on the nanosecond …