Alkoxy radicals see the light: new paradigms of photochemical synthesis
Alkoxy radicals are highly reactive species that have long been recognized as versatile
intermediates in organic synthesis. However, their development has long been impeded due …
intermediates in organic synthesis. However, their development has long been impeded due …
Exploring hydroperoxides in combustion: History, recent advances and perspectives
The aim of this paper is to review recent progress in detection and quantification of
hydroperoxides, and to understand their reaction kinetics in combustion environments …
hydroperoxides, and to understand their reaction kinetics in combustion environments …
Experimental and modeling investigation of the low-temperature oxidation of n-heptane
The low-temperature oxidation of n-heptane, one of the reference species for the octane
rating of gasoline, was investigated using a jet-stirred reactor and two methods of analysis …
rating of gasoline, was investigated using a jet-stirred reactor and two methods of analysis …
Recent advances in sulfur-and phosphorous-centered radical reactions for the formation of S–C and P–C bonds
XQ Pan, JP Zou, WB Yi, W Zhang - Tetrahedron, 2015 - Elsevier
Free radicals are important subjects in organic, bioorganic, medicinal, material, and
atmospheric chemistries. Synthetic utilities of free radicals have been well-accomplished in …
atmospheric chemistries. Synthetic utilities of free radicals have been well-accomplished in …
Methane, carbon monoxide, and ammonia in brown dwarfs and self-luminous giant planets
KJ Zahnle, MS Marley - The Astrophysical Journal, 2014 - iopscience.iop.org
We address disequilibrium abundances of some simple molecules in the atmospheres of
solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics …
solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics …
Autoignition measurements and a validated kinetic model for the biodiesel surrogate, methyl butanoate
The autoignition of methyl butanoate has been studied at 1 and 4 atm in a shock tube over
the temperature range 1250–1760 K at equivalence ratios of 1.5, 1.0, 0.5, and 0.25 at fuel …
the temperature range 1250–1760 K at equivalence ratios of 1.5, 1.0, 0.5, and 0.25 at fuel …
Rate constant estimation for C1 to C4 alkyl and alkoxyl radical decomposition
HJ Curran - International journal of chemical kinetics, 2006 - Wiley Online Library
Rate coefficients for alkyl and alkoxy radical decomposition are important in combustion,
biological, and atmospheric processes. In this paper, rate constant expressions for C1 C4 …
biological, and atmospheric processes. In this paper, rate constant expressions for C1 C4 …
Methyl formate oxidation: Speciation data, laminar burning velocities, ignition delay times, and a validated chemical kinetic model
The oxidation of methyl formate (CH3OCHO) has been studied in three experimental
environments over a range of applied combustion relevant conditions: 1. A variable …
environments over a range of applied combustion relevant conditions: 1. A variable …
Critical evaluation of thermochemical properties of C1–C4 species: updated group-contributions to estimate thermochemical properties
A review of literature on enthalpies of formation and molar entropies for alkanes, alkenes,
alcohols, hydroperoxides, and their associated radicals has been compiled and critically …
alcohols, hydroperoxides, and their associated radicals has been compiled and critically …
n-Heptane cool flame chemistry: Unraveling intermediate species measured in a stirred reactor and motored engine
This work identifies classes of cool flame intermediates from n-heptane low-temperature
oxidation in a jet-stirred reactor (JSR) and a motored cooperative fuel research (CFR) …
oxidation in a jet-stirred reactor (JSR) and a motored cooperative fuel research (CFR) …