Nanostructured block polymer electrolytes: tailoring self-assembly to unlock the potential in lithium-ion batteries

PM Ketkar, TH Epps III - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Ion-containing solid block polymer (BP) electrolytes can self-assemble into
microphase-separated domains to facilitate the independent optimization of ion conduction …

Electronic, Ionic, and Mixed Conduction in Polymeric Systems

EM Thomas, PH Nguyen, SD Jones… - Annual Review of …, 2021 - annualreviews.org
Polymers that simultaneously transport electrons and ions are paramount to drive the
technological advances necessary for next-generation electrochemical devices, including …

Reversible ion-conducting switch by azobenzene molecule with light-controlled sol–gel transitions of the PNIPAm ion gel

C Wang, W Dong, P Li, Y Wang, H Tu… - … Applied Materials & …, 2020 - ACS Publications
Exploring a simple, on-demanding method of manipulating ionic conduction of ionic liquids
with large amplitudes is a challenging task. Here, a reversible ion-conducting switch was …

Sequence-engineering polyethylene–polypropylene copolymers with high thermal conductivity using a molecular-dynamics-based genetic algorithm

T Zhou, Z Wu, HK Chilukoti… - Journal of Chemical …, 2021 - ACS Publications
Polymer sequence engineering is emerging as a potential tool to modulate material
properties. Here, we employ a combination of a genetic algorithm (GA) and atomistic …

Rheology and Miscibility of Linear/Hyperbranched Polydimethylsiloxane Blends and an Abnormal Decrease in Their Viscosity

SO Ilyin, VG Kulichikhin - Macromolecules, 2023 - ACS Publications
Linear polymers with the same monomer units and different molecular weights form miscible
blends considered to be single polymers, but the situation changes if one is hyperbranched …

Solid polymer electrolytes of ionic liquids via a bicontinuous ion transport channel for lithium metal batteries

WJ Cho, SK Cho, JH Lee, JH Yoon, S Kwon… - Journal of Materials …, 2023 - pubs.rsc.org
Solid polymer electrolytes (SPEs) are a key component of solid-state lithium metal batteries.
For attaining high ionic conductivity and high mechanical strength simultaneously …

Electrostatic interactions control the nanostructure of conjugated polyelectrolyte–polymeric ionic liquid blends

ML Le, DJ Grzetic, KT Delaney, KC Yang, S **e… - …, 2022 - ACS Publications
Polyelectrolyte complexation offers unique opportunities to compatibilize polymers with very
different backbone chemistries and to control the morphology of the resulting blend via …

Instability of the microemulsion channel in block copolymer-homopolymer blends

B Vorselaars, RKW Spencer, MW Matsen - Physical Review Letters, 2020 - APS
Field theoretic simulations are used to predict the equilibrium phase diagram of symmetric
blends of AB diblock copolymer with A-and B-type homopolymers. Experiments generally …

Self-Assembly of Partially Charged Diblock Copolymer-Homopolymer Ternary Blends

C Zheng, B Zhang, FS Bates, TP Lodge - Macromolecules, 2022 - ACS Publications
Ternary blends comprising a diblock copolymer and the corresponding homopolymers
provide ready access to a variety of morphologies, but the impact of charge on their phase …

Microemulsions as emerging electrolytes: the correlation of structure to electrochemical response

AE Imel, B Barth, DG Hayes, M Dadmun… - … Applied Materials & …, 2022 - ACS Publications
We describe the structural studies of microemulsions (μEs) prepared from water, toluene,
butanol, and polysorbate 20 (PS20) that we recently used as electrolytes. Small-angle …