Nonplanar porphyrins: synthesis, properties, and unique functionalities
Porphyrins are variously substituted tetrapyrrolic macrocycles, with wide-ranging biological
and chemical applications derived from metal chelation in the core and the 18π aromatic …
and chemical applications derived from metal chelation in the core and the 18π aromatic …
β-Pyrrole functionalized porphyrins: Synthesis, electronic properties, and applications in sensing and DSSC
Porphyrin is a class of tetrapyrrole compound with both natural and synthetic occurrence
and its derivatives perform a significant role as light harvesting antenna in the natural …
and its derivatives perform a significant role as light harvesting antenna in the natural …
Push–pull octaphenylporphyrins with mixed substituents pattern: Synthesis, redox, ultrafast dynamics and nonlinear optical studies
A new family of β-functionalized octaphenylporphyrins, MOPP (NO 2) Br 3 (M= 2H, Zn II, Ni II,
or Cu II, and OPP= octaphenylporphyrin) has been synthesized possessing unsymmetrical …
or Cu II, and OPP= octaphenylporphyrin) has been synthesized possessing unsymmetrical …
A2B2 type porphyrins with meso-donor groups: Synthesis, X-ray structures, DFT studies and photocatalytic application using sunlight
The trans-A 2 B 2 type porphyrins bearing thiophene linked N-butylcarbazole or N-
butylphenothiazine groups at the meso-positions were synthesized. Donor− acceptor (D− A) …
butylphenothiazine groups at the meso-positions were synthesized. Donor− acceptor (D− A) …
Fine-tuning metal and ligand-centered redox potentials of homoleptic bis-terpyridine complexes with 4′-aryl substituents
JC Dickenson, MKE Haley, JT Hyde, ZM Reid… - Inorganic …, 2021 - ACS Publications
Homoleptic transition-metal complexes of 2, 2': 6′, 2 ″-terpyridine (terpy) and substituted
derivatives of the form [M (R-terpy) 2] 2+ display a wide range of redox potentials that …
derivatives of the form [M (R-terpy) 2] 2+ display a wide range of redox potentials that …
Facile Synthesis of β-Tetracyano Vanadyl Porphyrin from Its Tetrabromo Analogue and Its Excellent Catalytic Activity for Bromination and Epoxidation Reactions
Complex 2, 3, 12, 13-tetracyano-5, 10, 15, 20-tetraphenylporphyrinatooxidovanadium
(IV){[VIVOTPP (CN) 4], 2} has been prepared by nucleophilic substitution of β-bromo groups …
(IV){[VIVOTPP (CN) 4], 2} has been prepared by nucleophilic substitution of β-bromo groups …
Synthesis, Structural, Electrochemical, and DFT Studies of Highly Substituted Nonplanar Ni (II) Porphyrins and Their Intensity-Dependent Third-Order Nonlinear …
We designed and successfully synthesized highly substituted electron-deficient nonplanar
Ni (II) porphyrins and their derivatives (1–7) in moderate to good yields. These derivatives …
Ni (II) porphyrins and their derivatives (1–7) in moderate to good yields. These derivatives …
Synthesis, spectral, and electrochemical studies of electronically tunable β-substituted porphyrins with mixed substituent pattern
Two new families of porphyrins with mixed substituent pattern, viz. 2-nitro-12, 13-
disubstituted-meso-tetraphenylporphyrins (H2TPP (NO2) X2, X= Ph, phenylethynyl (PE), 2 …
disubstituted-meso-tetraphenylporphyrins (H2TPP (NO2) X2, X= Ph, phenylethynyl (PE), 2 …
Robust Zinc (II) porphyrin Catalyst for Visible Light Induced C–H Arylation of Heteroarenes
Zinc (II) porphyrin catalyzed light induced C–H arylation of heteroarenes from anilines is
discussed. The method is nontoxic and efficient, using only 0.5 mol% of porphyrin catalyst to …
discussed. The method is nontoxic and efficient, using only 0.5 mol% of porphyrin catalyst to …
Strong two-photon absorption and ultrafast dynamics of meso-functionalized “push–pull” trans-A 2 BC porphyrins
A new series of “push–pull” meso-substituted trans-A2BC porphyrins, where A= mesityl, B=
phenothiazine (push) and C= o/p-nitrophenyl moiety (pull) and M= 2H, Ni (II), Cu (II), and Zn …
phenothiazine (push) and C= o/p-nitrophenyl moiety (pull) and M= 2H, Ni (II), Cu (II), and Zn …