In the past decade, alternative benign organic methodologies have become an imperative
part of organic syntheses and chemical reactions. The various new and innovative …

Achieving high levels of chemoselectivity has been the Achilles' heel of chemical synthesis.
The excitement generated by the successful realization of chemoselective strategies …

Catalytic C–H activation has emerged as a powerful tool for sustainable syntheses. In the
recent years, notable success was achieved with the development of cobalt-catalyzed C–H …

The linear or branched allyl moieties on aromatic rings are well-known as ubiquitous
structural motifs found in a range of natural products and medicinally relevant molecules …

We report the direct amidation of arene C–H bonds using sulfonyl azides as the amino
source to release N2 as the single byproduct. The reaction is catalyzed by a cationic …

The Co (III)-catalyzed direct C–H amidation of arenes has been developed using O-
acylcarbamates as a convenient amino source. This reaction proceeded in high efficiency …

A cobalt-catalyzed C–H cyanation reaction of arenes has been developed using N-
cyanosuccinimide as a new electrophilic cyanating agent. The reaction proceeds with high …

Radical translocation processes triggered by nitrogen-centered radicals (NCRs), such as 1,
5-hydrogen atom transfers (1, 5-HAT), demonstrated by the well-established Hofmann …

A cationic cobalt (III)‐catalyzed direct C H amidation of unactivated (hetero) arenes and
alkenes by using 1, 4, 2‐dioxazol‐5‐ones as the amidating reagent has been developed …

Cp* CoIII-catalyzed C–H allylation of various aromatic C–H bonds using allyl alcohols as
allylating reagents is described. Improved reaction conditions using fluorinated alcohol …